Experiment on laminar combustion characteristics of n-tetradecane
-
摘要: 采用定容燃烧实验平台获得初始压力为0.1 MPa、初始温度为420、450 K和480 K,当量比为0.8~1.4工况下正十四烷/空气预混气层流燃烧速度和马克斯坦长度,并分析了初始温度、当量比等因素的影响。研究发现:初始温度和当量比的增加对预混气球形火焰稳定性影响较小,在初始温度为480 K、当量比为1.3工况下,火焰内部无裂纹或胞状结构;初始温度的增加能够加快火焰传播速度,促进火焰锋面形成,其影响在稀混合气中更为显著;随着当量比的增加,正十四烷预混燃烧火焰马克斯坦长度减小,火焰稳定性变差;随着初始温度的增加,正十四烷马克斯坦长度减小,无拉伸火焰传播速度和层流燃烧速度增加,另外,与RP-3航空煤油层流燃烧速度对比发现,正十四烷层流燃烧速度整体偏高。
-
关键词:
- 层流燃烧速度 /
- 马克斯坦长度 /
- 正十四烷/空气预混气 /
- 初始温度 /
- 当量比
Abstract: The laminar burning velocity and Markstein length of n-tetradecane/air mixture were obtained under initial pressure of 0.1 MPa, initial temperatures of 420, 450 K and 480 K within a wide equivalence ratio range from 0.8 to 1.4 in a constant volume chamber, and the effects of initial temperature and equivalence ratio were analyzed. The results showed that the increase of initial temperature and equivalence ratio had little effect on the stability of the flame propagation images. Under the initial temperature of 480 K and equivalence ratio of 1.3, there was no crack or cellular structure in the flame. The effect that the increase of initial temperature can increase the flame propagation speed and promote the formation of flame front was observed, which was more significant in the lean mixture. With the increase of equivalence ratio, the Markstein length of n-tetradecane/air mixture decreased and the flame stability became worse. With the increase of temperature, the Markstein length decreased, and the unstretched flame speed and laminar burning velocity increased. In addition, compared with the laminar burning velocity of RP-3 kerosene, the laminar burning velocity of n-tetradecane was higher under most conditions. -
[1] 马洪安,解茂昭,曾文,等.航空发动机燃烧室燃烧过程与排放物生成的反应动力学数值模拟[J].航空动力学报,2013,28(2):297-306. MA Hongan,XIE Maozhao,ZENG Wen,et al.Reaction kinetic numerical simulation of combustion process and emission formation in aero-engine combustor[J].Journal of Aerospace Power,2013,28(2):297-306.(in Chinese) [2] 蔡文祥,赵坚行,胡好生,等.数值研究环形回流燃烧室紊流燃烧流场[J].航空动力学报,2010,25(5):993-998. CAI Wenxiang,ZHAO Jianxing,HU Haosheng,et al.Numerical research of turbulent combustion in reversed-type annular combustor[J].Journal of Aerospace Power,2010,25(5):993-998.(in Chinese) [3] 肖保国,杨顺华,赵慧勇,等.RP-3航空煤油燃烧的详细和简化化学动力学模型[J].航空动力学报,2010,25(9):1948-1955. XIAO Baoguo,YANG Shunhua,ZHAO Huiyong,et al.Detailed and reduced chemical kinetic mechanisms for RP-3 aviation kerosene combustion[J].Journal of Aerospace Power,2010,25(9):1948-1955.(in Chinese) [4] 郑东,于维铭,钟北京.RP-3航空煤油替代燃料及其化学反应动力学模型[J].物理化学学报,2015,31(4):636-642. ZHENG Dong,YU Weiming,ZHONG Beijing.RP-3 aviation kerosene surrogate fuel and the chemical reaction kinetic model[J].Acta Physico-Chimica Sinica,2015,31(4):636-642.(in Chinese) [5] 戴超,王亚军,颜应文,等.一种基于敏感性分析的RP-3替代燃料简化机理[J].南京航空航天大学学报,2015,47(4):579-587. DAI Chao,WANG Yajun,YAN Yingwen,et al.Reduced mechanism of surrogate fuel for RP-3 kerosene based on sensitivity analysis[J].Journal of Nanjing University of Aeronautics and Astronautics,2015,47(4):579-587.(in Chinese) [6] CHARLES K W,WILLIAM J P,OLIVIER H,et al.A comprehensive detailed chemical kinetic reaction mechanism for combustion of n-alkane hydrocarbons from n-octane to n-hexadecane[J].Combustion and Flame,2009,156(1):181-199. [7] 刘建文,姚通,钟北京,等.正十四烷低温点火及燃烧机理的构建和简化[J].推进技术,2017,38(1):119-124. LIU Jianwen,YAO Tong,ZHONG Beijing,et al.Development and reduction of n-tetradecane mechanism for low temperature ignition and combustion[J].Journal of Propulsion Technology,2017,38(1):119-124.(in Chinese) [8] SHEN H S,STEINBERG J,VANDEROVER J,et al.A shock tube study of the ignition of n-heptane,n-decane,n-dodecane,and n-tetradecane at elevated pressures[J].Energy and Fuels,2009,23(5):2482-2489. [9] CAVALIERE A,CIAJOLO A,D’ANNA A,et al.Autoignition of n-heptane and n-tetradecane in engine-like conditions[J].Combustion and Flame,1993,93(3):279-286. [10] ZENG M R,YUAN W H,LI W,et al.A comprehensive experimental and kinetic modeling study of n-tetradecane combustion[J].Energy and Fuels,2017,31(11):12712-12720. [11] LI B,LIU N,ZHAO R,et al.Flame propagation of mixtures of air with high molecular weight neat hydrocarbons and practical jet and diesel fuels[J].Proceedings of the Combustion Institute,2013,34(1):727-733. [12] MZ-AHMED A,DAGAUT P,DAYMA G,et al.Experimental study of the oxidation of n-tetradecane in a jet-stirred reactor (JSR) and detailed chemical kinetic modeling[J].Combustion Science and Technology,2014,186(4/5):594-606. [13] HU E J,HUANG Z H,HE J J,et al.Experimental and numerical study on laminar burning characteristics of premixed methane/hydrogen/air flames[J].International Journal of Hydrogen Energy,2009,34(11):4876-4888. [14] ZENG W,LIU J,LIU Y,et al.The effect of hydrogen addition on the combustion characteristics of RP-3 kerosene/air premixed flames[EB/OL].[2020-02-04].http://doi.org/10.3390/en10081107. [15] HUANG Z,WANG Q,YU J,et al.Measurement of laminar burning velocity of dimethyl ether-air premixed mixtures[J].Fuel,2007,86(15):2360-2366. [16] BURKE M P,CHEN Z,JU Y G,et al.Effect of cylindrical confinement on the determination of laminar flame speeds using outwardly propagating flames[J].Combustion and Flame,2009,156(4):771-779. [17] BRADLEY D,HICKS R A,LAWES M,et al.The measurement of laminar burning velocities and Markstein lengths for iso-octane/air and iso-octane/n-heptane/air mixtures at elevated temperatures and pressures in an explosion bomb[J].Combustion and Flame,1998,115(1):126-144. [18] FRANKEL M L,SIVASHINSKY G I.On effects due to thermal expansion and Lewis number in spherical flame propagation[J].Combustion Science and Technology,1983,31(3/4):131-138. [19] CHEN Z.On the extraction of laminar flame speed and Markstein length from outwardly propagating spherical flames[J].Combustion and Flame,2011,158(2):291-300. [20] 刘宇,孙震,汤卓,等.初始温度对CH4/RP-3航空煤油混合燃料层流燃烧特性的影响[J].航空动力学报,2019,34(2):348-356.
点击查看大图
计量
- 文章访问数: 237
- HTML浏览量: 4
- PDF量: 359
- 被引次数: 0