Secondary combustion and inhibition mechanism in gas-steam ejection system
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摘要:
基于燃气-蒸汽弹射系统1∶3缩比模型,采用数值模拟方法系统分析了发射筒内流场特性、二次燃烧现象及其抑制机理。结果表明:二次燃烧主要发生在发射筒内涡旋区与滞止区;低水雾燃气比条件下二次燃烧易发生;随着水雾量增加,蒸发吸热与自由基稀释作用增强,可有效延缓甚至抑制二次燃烧,但过高水雾量会导致系统温度下降并削弱做功能力。为兼顾抑制效果与发射性能,进一步研究了低水雾燃气比下含钾抑制剂的作用。结果显示:抑制剂引入后筒内平均OH质量分数降低约3个数量级,显著削弱了自由基活性,即使在低用量下亦能有效抑制二次燃烧。研究结果为燃气-蒸汽弹射系统的安全设计与工程应用提供了参考。
Abstract:Based on a 1∶3 scaled model of the gas-steam ejection system, this study systematically analyzes the in-tube flow characteristics, secondary combustion phenomena, and inhibition mechanisms using numerical simulations. The results indicate that secondary combustion primarily occurs in the vortex and stagnation zones inside the tube, and it is more likely to take place under low water-mist-to-gas ratios. As the amount of water mist increases, the effects of evaporation heat absorption and free radical dilution are enhanced, which can effectively delay or even suppress secondary combustion. However, excessive water mist leads to an over-decrease in temperature and weakens the system’s power output capability. To balance inhibition effectiveness and ejection performance, the effect of potassium-containing inhibitors under low water-mist-to-gas ratios was further investigated. The results show that after the introduction of the inhibitor, the average OH mass fraction inside the tube decreases by about three orders of magnitude, significantly weakening radical activity. Even with a small dosage, the inhibitor effectively suppresses secondary combustion. The findings provide theoretical and engineering references for the safe design and practical application of gas-steam ejection systems.
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表 1 钾基组分参与的主要基元反应
Table 1. Key elementary reactions of potassium-based species
序号 化学反应 A n Ea 1 K+OH+M=KOH+M 1.42×1018 0 0 2 KOH+H=K+H2O 1.79×10−11 0 1 987 3 K+O2+M=KO2+M 1.14×102 −2.68 596 4 KO2+H=KO+OH 2.21×1012 0.5 0 5 KO+H=K+OH 2.32×10−11 1.97 571 6 KO+OH=KOH+O 2.00×1013 0 0 表 2 模拟工况参数汇总表
Table 2. Summary of simulation condition parameters
仿真工况 入口
总压/MPa筒内
初压/MPa水雾
燃气比是否添加
含钾抑制剂1 p0 p1 7.5ω 否 2 p0 p1 8ω 否 3 p0 p1 10ω 否 4 p0 p1 4ω 是 -
[1] 惠卫华, 杨玉磊, 马艳杰, 等. 燃气-蒸汽弹射喷水多相汽化计算及影响分析[J]. 弹箭与制导学报, 2021, 41(1): 113-116, 119. HUI Weihua, YANG Yulei, MA Yanjie, et al. Multiphase vaporization calculation and influence analysis of gas-steam ejection water injection process[J]. Journal of Projectiles, Rockets, Missiles and Guidance, 2021, 41(1): 113-116, 119. (in Chinese doi: 10.15892/j.cnki.djzdxb.2021.01.025HUI Weihua, YANG Yulei, MA Yanjie, et al. Multiphase vaporization calculation and influence analysis of gas-steam ejection water injection process[J]. Journal of Projectiles, Rockets, Missiles and Guidance, 2021, 41(1): 113-116, 119. (in Chinese) doi: 10.15892/j.cnki.djzdxb.2021.01.025 [2] 王凯, 苟金澜, 乐贵高, 等. 燃气-蒸汽弹射气液两相流场流动耦合特性研究[J]. 固体火箭技术, 2023, 46(6): 955-962. WANG Kai, GOU Jinlan, LE Guigao, et al. Study on flow coupling characteristics of gas-liquid two-phase flow field in gas-steam ejection[J]. Journal of Solid Rocket Technology, 2023, 46(6): 955-962. (in ChineseWANG Kai, GOU Jinlan, LE Guigao, et al. Study on flow coupling characteristics of gas-liquid two-phase flow field in gas-steam ejection[J]. Journal of Solid Rocket Technology, 2023, 46(6): 955-962. (in Chinese) [3] 刘永泉, 郗安民, 刘鸿飞. 导弹燃气-蒸汽弹射发射技术概述[J]. 飞航导弹, 2009(12): 23-25, 29. LIU Yongquan, XI Anmin, LIU Hongfei. Overview of missile gas-steam ejection launch technology[J]. Aerodynamic Missiles Journal, 2009(12): 23-25, 29. (in ChineseLIU Yongquan, XI Anmin, LIU Hongfei. Overview of missile gas-steam ejection launch technology[J]. Aerodynamic Missiles Journal, 2009(12): 23-25, 29. (in Chinese) [4] 李建林, 王瑞臣, 李伟刚, 等. 潜射导弹变深度弹射技术综述[J]. 飞航导弹, 2019(7): 69-73. LI Jianlin, WANG Ruichen, LI Weigang, et al. Summary of variable depth ejection technology for submarine-launched missiles[J]. Aerodynamic Missile Journal, 2019(7): 69-73. (in ChineseLI Jianlin, WANG Ruichen, LI Weigang, et al. Summary of variable depth ejection technology for submarine-launched missiles[J]. Aerodynamic Missile Journal, 2019(7): 69-73. (in Chinese) [5] 李仁凤. 燃气—蒸汽弹射流场与弹道特性研究[D]. 南京: 南京理工大学, 2017. LI Renfeng. Research on the flow field and ballistic characteristics of the gas-steam ejection[D]. Nanjing: Nanjing University of Science and Technology, 2017. (in ChineseLI Renfeng. Research on the flow field and ballistic characteristics of the gas-steam ejection[D]. Nanjing: Nanjing University of Science and Technology, 2017. (in Chinese) [6] 胡晓磊, 乐贵高, 李仁凤, 等. 燃气弹射发射筒内燃气-空气二次燃烧现象研究[J]. 弹道学报, 2014, 26(4): 76-81. HU Xiaolei, LE Guigao, LI Renfeng, et al. Study on secondary combustion of jet-flow and air inner tube of gas ejection launcher[J]. Journal of Ballistics, 2014, 26(4): 76-81. (in ChineseHU Xiaolei, LE Guigao, LI Renfeng, et al. Study on secondary combustion of jet-flow and air inner tube of gas ejection launcher[J]. Journal of Ballistics, 2014, 26(4): 76-81. (in Chinese) [7] Prediction of the launch pulse for gas generator launched missiles[R]. AIAA-1988-3290, 1988. [8] 张仁军, 鲍福廷. 两种不同注水方式的燃气蒸汽式发射系统内弹道性能比较[J]. 固体火箭技术, 2005, 28(1): 5-9. ZHANG Renjun, BAO Futing. Comparison of internal ballistic properties between gas and steam launching systems in two different modes of water injection[J]. Journal of Solid Rocket Technology, 2005, 28(1): 5-9. (in ChineseZHANG Renjun, BAO Futing. Comparison of internal ballistic properties between gas and steam launching systems in two different modes of water injection[J]. Journal of Solid Rocket Technology, 2005, 28(1): 5-9. (in Chinese) [9] 赵世平, 鲍福廷. 燃气蒸汽式发射系统内弹道若干问题研究[J]. 固体火箭技术, 2003, 26(3): 7-10. ZHAO Shiping, BAO Futing. Analysis of several coefficients of interior ballistic evaluation for gas and steam launching system[J]. Journal of Solid Rocket Technology, 2003, 26(3): 7-10. (in ChineseZHAO Shiping, BAO Futing. Analysis of several coefficients of interior ballistic evaluation for gas and steam launching system[J]. Journal of Solid Rocket Technology, 2003, 26(3): 7-10. (in Chinese) [10] KIM H M, BAE S H, PARK C H, et al. Thermo-fluid dynamic and missile-motion performance analysis of gas-steam launch system utilizing multiphase flow model and dynamic grid system[J]. Journal of the Korean Society of Propulsion Engineers, 2017, 21(2): 48-59. [11] 苗佩云, 袁曾凤. 筒内复杂流场三维数值模拟[J]. 弹箭与制导学报, 2004, 24(1): 71-72, 84. MIAO Peiyun, YUAN Zengfeng. Three-dimensional simulation for complicated flow of a canister[J]. Journal of Projectiles, Rockets, Missiles and Guidance, 2004, 24(1): 71-72, 84. (in ChineseMIAO Peiyun, YUAN Zengfeng. Three-dimensional simulation for complicated flow of a canister[J]. Journal of Projectiles, Rockets, Missiles and Guidance, 2004, 24(1): 71-72, 84. (in Chinese) [12] 芮守祯, 邢玉明. 导弹弹射装置冷却器中液滴轨迹及特性的数值模拟[J]. 舰船科学技术, 2010, 32(4): 113-116. RUI Shouzhen, XING Yuming. The simulation of droplet trajectory and properties in cooler of missile launch system[J]. Ship Science and Technology, 2010, 32(4): 113-116. (in Chinese doi: 10.3404/j.issn.1672-7649.2010.04.028RUI Shouzhen, XING Yuming. The simulation of droplet trajectory and properties in cooler of missile launch system[J]. Ship Science and Technology, 2010, 32(4): 113-116. (in Chinese) doi: 10.3404/j.issn.1672-7649.2010.04.028 [13] 肖虎斌, 赵世平. 燃气蒸汽式发射动力装置复杂内流场数值模拟[J]. 固体火箭技术, 2009, 32(4): 392-395. XIAO Hubin, ZHAO Shiping. Numerical simulation of the complex flow field in combustion gas-steam launching system[J]. Journal of Solid Rocket Technology, 2009, 32(4): 392-395. (in ChineseXIAO Hubin, ZHAO Shiping. Numerical simulation of the complex flow field in combustion gas-steam launching system[J]. Journal of Solid Rocket Technology, 2009, 32(4): 392-395. (in Chinese) [14] 白俊华, 胡馨博. 进气角度和初始粒径对发射筒内流动特性的影响[J]. 固体火箭技术, 2013, 36(2): 165-169. BAI Junhua, HU Xinbo. Impact of injection angle and initial particles diameter on interior flow characteristic of silo[J]. Journal of Solid Rocket Technology, 2013, 36(2): 165-169. (in Chinese doi: 10.7673/j.issn.1006-2793.2013.02.005BAI Junhua, HU Xinbo. Impact of injection angle and initial particles diameter on interior flow characteristic of silo[J]. Journal of Solid Rocket Technology, 2013, 36(2): 165-169. (in Chinese) doi: 10.7673/j.issn.1006-2793.2013.02.005 [15] 刘伯伟, 姜毅. 汽化效应对燃气蒸汽式弹射气液两相流场的影响[J]. 固体火箭技术, 2014, 37(2): 156-160. LIU Bowei, JIANG Yi. Influence of vaporization effect on gas-liquid two-phase flow field of ejection in combustion gas and vapor mode[J]. Journal of Solid Rocket Technology, 2014, 37(2): 156-160. (in ChineseLIU Bowei, JIANG Yi. Influence of vaporization effect on gas-liquid two-phase flow field of ejection in combustion gas and vapor mode[J]. Journal of Solid Rocket Technology, 2014, 37(2): 156-160. (in Chinese) [16] 李仁凤, 乐贵高, 马大为, 等. 结构参数对燃气-蒸汽弹射载荷和弹道影响[J]. 上海交通大学学报, 2016, 50(11): 1789-1794. LI Renfeng, LE Guigao, MA Dawei, et al. Effect of structural parameters on gas-steam ejection power system[J]. Journal of Shanghai Jiao Tong University, 2016, 50(11): 1789-1794. (in Chinese doi: 10.16183/j.cnki.jsjtu.2016.11.022LI Renfeng, LE Guigao, MA Dawei, et al. Effect of structural parameters on gas-steam ejection power system[J]. Journal of Shanghai Jiao Tong University, 2016, 50(11): 1789-1794. (in Chinese) doi: 10.16183/j.cnki.jsjtu.2016.11.022 [17] 宋勇, 翟燕. 燃气-蒸汽发射系统内两相流动与传热特性研究[J]. 舰船科学技术, 2023, 45(24): 212-217. SONG Yong, ZHAI Yan. Research on two-phase flow and heat transfer characteristics in gas-steam launch system[J]. Ship Science and Technology, 2023, 45(24): 212-217. (in ChineseSONG Yong, ZHAI Yan. Research on two-phase flow and heat transfer characteristics in gas-steam launch system[J]. Ship Science and Technology, 2023, 45(24): 212-217. (in Chinese) [18] 胡晓磊, 乐贵高, 马大为, 等. 环形腔对燃气弹射初容室二次燃烧影响数值研究[J]. 兵工学报, 2015, 36(6): 1024-1032. HU Xiaolei, LE Guigao, MA Dawei, et al. Numerical study on influence of annular cavity on secondary combustion of gas-ejection initial cavity[J]. Acta Armamentarii, 2015, 36(6): 1024-1032. (in ChineseHU Xiaolei, LE Guigao, MA Dawei, et al. Numerical study on influence of annular cavity on secondary combustion of gas-ejection initial cavity[J]. Acta Armamentarii, 2015, 36(6): 1024-1032. (in Chinese) [19] 胡晓磊, 孙船斌, 郭佳肄, 等. 二次燃烧对燃气弹射初容室载荷影响数值研究[J]. 兵器装备工程学报, 2020, 41(11): 70-73. HU Xiaolei, SUN Chuanbin, GUOJIA Yi, et al. Numerical simulation of secondary-combustion influence on gas-ejection load in initial chamber[J]. Journal of Ordnance Equipment Engineering, 2020, 41(11): 70-73. (in Chinese doi: 10.11809/bqzbgcxb2020.11.013HU Xiaolei, SUN Chuanbin, GUOJIA Yi, et al. Numerical simulation of secondary-combustion influence on gas-ejection load in initial chamber[J]. Journal of Ordnance Equipment Engineering, 2020, 41(11): 70-73. (in Chinese) doi: 10.11809/bqzbgcxb2020.11.013 [20] 胡晓磊, 王辉, 乐贵高, 等. 二次燃烧对燃气弹射载荷和内弹道影响数值研究[J]. 固体火箭技术, 2015, 38(6): 776-781. HU Xiaolei, WANG Hui, LE Guigao, et al. Numerical study of effect of secondary combust-ion on gas ejection load and internal ballistics[J]. Journal of Solid Rocket Technology, 2015, 38(6): 776-781. (in Chinese doi: 10.7673/j.issn.1006-2793.2015.06.005HU Xiaolei, WANG Hui, LE Guigao, et al. Numerical study of effect of secondary combust-ion on gas ejection load and internal ballistics[J]. Journal of Solid Rocket Technology, 2015, 38(6): 776-781. (in Chinese) doi: 10.7673/j.issn.1006-2793.2015.06.005 [21] TABEJAMAAT S, JU Y, NIIOKA T. Numerical sim-ulation of secondary combustion of hydrogen injected from preburner into supersonic airflow[J]. AIAA Journal, 1997, 35(9): 1441-1447. doi: 10.2514/2.266 [22] 蒲鹏宇, 穆洪斌, 何定洲, 等. 二次燃烧对自力弹射内弹道影响分析[J]. 宇航总体技术, 2024, 8(2): 1-5. PU Pengyu, MU Hongbin, HE Dingzhou, et al. The impact of afterburning on internal ballistic of self-ejection[J]. Astronautical Systems Engineering Technology, 2024, 8(2): 1-5. (in ChinesePU Pengyu, MU Hongbin, HE Dingzhou, et al. The impact of afterburning on internal ballistic of self-ejection[J]. Astronautical Systems Engineering Technology, 2024, 8(2): 1-5. (in Chinese) [23] HOORELBEKE P, VAN WINGERDEN K, GEXCON A S. Flame inhibition by potassium-containing com-pounds[J]. Journal of Hazardous Materials, 2019. [24] WANG Tao, MENG Fan, YI Weizhai, et al. Investigation on the deflagration inhibition effects of potassium salt-modified dry water on CH4/air mixture[J]. Journal of Loss Prevention in the Process Industries, 2025, 96: 105616. doi: 10.1016/j.jlp.2025.105616 [25] 刘皓, 张天巍, 夏登友, 等. 水与K2CO3的协同灭火作用[J]. 燃烧科学与技术, 2018, 24(1): 9-14. LIU Hao, ZHANG Tianwei, XIA Dengyou, et al. Synergistic effect of fire extinguishing by water and K2CO3[J]. Journal of Combustion Science and Technology, 2018, 24(1): 9-14. (in Chinese doi: 10.11715/rskxjs.R201701001LIU Hao, ZHANG Tianwei, XIA Dengyou, et al. Synergistic effect of fire extinguishing by water and K2CO3[J]. Journal of Combustion Science and Technology, 2018, 24(1): 9-14. (in Chinese) doi: 10.11715/rskxjs.R201701001 [26] Ó CONAIRE M, CURRAN H J, SIMMIE J M, et al. A comprehensive modeling study of hydrogen oxidation[J]. International Journal of Chemical Kinetics, 2004, 36(11): 603-622. doi: 10.1002/kin.20036 [27] SMITH G P, GOLDEN D M, FRENKLACH M, et al. GRI-Mech 3.0: an optimized detailed chemical reaction mechanism for methane combustion[R/OL]. Berkeley, US: Gas Research Institute, 1999. [28] DOUNIA O, VERMOREL O, JARAVEL T, et al. Time scale analysis of the homogeneous flame inhibition by alkali metals[J]. Proceedings of the Combustion Institute, 2021, 38(2): 2371-2378. doi: 10.1016/j.proci.2020.06.030 [29] KÉROMNÈS A, METCALFE W K, HEUFER K A, et al. An experimental and detailed chemical kinetic modeling study of hydrogen and syngas mixture oxidation at elevated pressures[J]. Combustion and Flame, 2013, 160(6): 995-1011. doi: 10.1016/j.combustflame.2013.01.001 [30] HSUEH M H, LAI C J, HSIEH M C, et al. Effect of water vapor injection on the performance and emissions characteristics of a spark-ignition engine[J]. Sustainability, 2021, 13(16): 9229. doi: 10.3390/su13169229 [31] WANG M R, TIAN S N, TURKSON R F, et al. Water injection for higher engine performance and lower emissions[J]. Journal of the Energy Inst-itute, 2017, 90(2): 285-299. doi: 10.1016/j.joei.2015.12.003 -

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