Abstract:
According to the requirement for high-efficient production of high quality solid rocket motor shell, the epoxy resin formulation with different functionalities was studied by focusing on its formulation design and mechanical properties. The curing characteristic temperature, curing reaction kinetics and pot life were tested by DSC (differential scanning calorimetry) and viscosity test, respectively, the unidirectional laminates and NOL (the Naval Ordnance Laboratory) rings were prepared to test and analyze the properties of composites. The results showed that the epoxy resin with three functionalities can meet the requirements of high efficient wet winding. When the mass fraction of TDE-85 with three functionalities was 25%, the comprehensive properties reached the optimum, the tensile strength (973 MPa), the bending strength (115 MPa) and the glass transition temperature (466 K) increased by 363%, 159% and 258% respectively, while the applicable period was 120 min. The resin system had good adaptability to fibers, demonstrated by the excellent properties of composites, about 256 GPa in tensile strength and 744 MPa in interlaminar shear strength of the NOL rings, respectively. The utilization ratio of fiber strength reached 766%, demonstrating that the epoxy resin system was suitable for the wet winding process of the solid rocket motor.