Volume 36 Issue 10
Oct.  2021
Turn off MathJax
Article Contents
Article Navigation >  Journal of Aerospace Power  > 2021  >  36(10): 2114-2125
ZHOU Zhou, HUAN Dajun, LI Yong, LI Lisha, LIU Hongquan, JIAO Yang. Bismaleimide resin modification for Z-pin high efficiency pultrusion[J]. Journal of Aerospace Power, 2021, 36(10): 2114-2125. doi: 10.13224/j.cnki.jasp.20200479
Citation: ZHOU Zhou, HUAN Dajun, LI Yong, LI Lisha, LIU Hongquan, JIAO Yang. Bismaleimide resin modification for Z-pin high efficiency pultrusion[J]. Journal of Aerospace Power, 2021, 36(10): 2114-2125. doi: 10.13224/j.cnki.jasp.20200479
shu

Bismaleimide resin modification for Z-pin high efficiency pultrusion

doi: 10.13224/j.cnki.jasp.20200479

  • College of Materials Science and Technology，Nanjing University of Aeronautics and Astronautics，Nanjing 210016，China

  • Received Date: 2020-11-09
  • Publish Date: 2021-10-28
    Abstract
  • To meet the demand of bismaleimide resin （BMI） for Z-pin high efficient pultrusion applications，its properties such as low viscosity （500 mPa·s），heat resistance （glass transition temperature is more than 200 ℃），fast curing and good toughness shall be required.TDE-85 epoxy resin （EP） was used to reduce the viscosity of BMI，and further modifiers were added to improve the heat resistance and mechanical properties of the resin.Viscosity test，differential scanning calorimetry，thermogravimetric analysis and mechanical properties test were used to study the curing process，curing reaction kinetics，heat resistance and basic mechanical properties of the resin，and the best resin system was selected for the preparation of Z-pin and performance test and analysis.The results showed that the addition of TDE-85 epoxy resin can effectively reduce the viscosity of the resin system and meet the demand of high efficiency pultrusion process.The addition of modifier diphenylmethane （MDI） improved the toughness and heat resistance of EP-BMI system.The glass transition temperature was 251 ℃，and the comprehensive performance was optimized.The tensile strength and impact strength of the cast body were 66 MPa and 21 kJ/m2，which increased by 38% and 53%，respectively.The short beam shear strength of Z-pin was 67 MPa and the bond strength with the substrate was 31.2 MPa.In summary，the modified resin system can fully meet the process requirements and performance requirements of high efficiency pultrusion of Z-pin.It has good engineering application value.

     

    • FullText(HTML)
  • loading
    • References(25)
  • [1]
    张向阳,李勇,褚奇奕,等.碳纤维/酚醛树脂体系Z-pin加捻拉挤工艺及其性能[J].航空动力学报,2015,30（7）:1638-1644.
    [2]
    包建文,蒋诗才,张代军.航空碳纤维树脂基复合材料的发展现状和趋势[J].科技导报,2018,36（19）:52-63.
    [3]
    GAYE K,ERDEM S.Impact resistance of Z-pin-reinforced sandwich composites[J].Journal of Composite Materials,2019,53（26/27）:3681-3699.
    [4]
    冯波,王晓洁,惠雪梅.复合材料Z-pin增强技术研究现状[J].玻璃钢/复合材料,2012（2）:82-85.
    [5]
    LIU S Y,CHEN Y Z,CHEN P，et al.Properties of novel bismaleimide resins and thermal ageing effects on the ILSS performance of their carbon fibre bismaleimide composites[J].Polymer Composites,2019,40（Suppl.2）:1283-1293.
    [6]
    宣海军,陆晓,洪伟荣,等.航空发动机机匣包容性研究综述[J].航空动力学报,2010,25（8）:1860-1870.
    [7]
    宋健,温卫东.不同温度下树脂基复合材料层合板力学性能试验[J].航空动力学报,2016,31（4）:1006-1018.
    [8]
    张勇波,傅惠民,王治华.CCF300/QY8911单向纤维增强复合材料纵向压缩性能预测[J].航空动力学报,2013,28（6）:1231-1235.
    [9]
    李健芳,郭鸿俊,高杨,等.MT300/802双马树脂基复合材料固化工艺及高温力学性能[J].宇航材料工艺,2019,49（4）:34-40.
    [10]
    赵渠森.QY8911树脂系列及其工程应用[J].工程塑料应用,1995（1）:1-8.
    [11]
    GU A J.High performance bismaleimide/cyanate ester hybrid polymer networks with excellent dielectric properties[J].Composites Science and Technology,2006,66（11）:1749-1755.
    [12]
    JIANG H,WANG R M,SHAMEEL F,et al.Optimization and preparation of an allyl phenoxy-modified bismaleimide resin[J].High Performance Polymers,2016,28（6）:677-684.
    [13]
    LIU C,DONG Y F,LIN Y,et al.Enhanced mechanical and tribological properties of graphene/bismaleimide composites by using reduced graphene oxide with non-covalent functionalization[J].Composites Part B,2019,165（2）:491-499.
    [14]
    ZOU Q,XIAO F,GU S Q,et al.Toughening of bismaleimide resin based on the self-assembly of flexible aliphatic side chains[J].Industrial and Engineering Chemistry Research,2019,58（36）:16526-16531.
    [15]
    QU C Y,CHANG J Y,LIU C W,et al.Novel allyl and propenyl monomers for modification of the bismaleimide resins,with excellent dielectric properties and high glass transition temperatures[J].High Performance Polymers,2020,32（1）:116-126.
    [16]
    WANG K X,WANG Y Y,CHEN P,et al.Novel bismaleimide resins modified by allyl compound containing liquid crystalline structure[J].Advances in Polymer Technology,2018,37（1）:281-289.
    [17]
    王居临,王钧.环氧树脂改性双马来酰亚胺复合材料力学性能及耐热性能研究[J].玻璃钢/复合材料,2014（5）:25-31.
    [18]
    WU G L,KOU K C,CHAO M,et al.Preparation and characterization of bismaleimide-triazine/epoxy interpenetrating polymer networks[J].Thermochimica Acta,2012,537:44-50.
    [19]
    JENA R K,YUE C Y,SK M M,et al.A novel high performance bismaleimide/diallyl bisphenol A （BMI/DBA） –epoxy interpenetrating network resin for rigid riser application[J].RSC Advances,2015,97（5）:79888-79897.
    [20]
    祝君军,文友谊,何屹,等.改性双马来酰亚胺树脂的化学流变性研究[J].塑料工业,2018,46（8）:85-88.
    [21]
    ROZENBERG B A,DZHAVADYAN E A,MORGAN R,et al.High‐performance bismaleimide matrices:cure kinetics and mechanism[J].Polymers for Advanced Technologies,2002,13（10）:837-844.
    [22]
    LIU X Y,LI L,CHEN Z B,et al.Curing behavior,thermal,and mechanical properties of N,N′-（4,4′-diphenylmethane）bismaleimide/2,2′-diallylbisphenol A/3-allyl-5,5-dimethylhydantoin resin system[J].High Performance Polymers,2020,32（6）:631-644.
    [23]
    周浩然,荆佳奇,王德志,等.双马来酰亚胺工艺改性及性能[J].复合材料学报,2020,37（6）:1278-1284.
    [24]
    HUANG F W,HUANG F R,ZHOU Y,et al.Preparation and properties of bismaleimide resins modified with hydrogen silsesquioxane and dipropargyl ether and their composites[J].Polymer Journal,2010,42（3）:261-267.
    [25]
    DAI S C,YAN W,LIU H Y,et al.Experimental study on Z-pin bridging law by pullout test[J].Composites Science and Technology,2004,64（16）:2451-2457.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF(5337.0KB)
    XML

    Article Metrics

    Article views (323) PDF downloads(236) Cited by()
    Proportional views
    Related

    Copyright © 《Journal of Aerospace Power》 All Rights Reserved.

    Supported by: Beijing Renhe Information Technology Co., Ltd.  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return