| Citation: | YANG Ren, YANG Xiaohong, SHAO Xiaofeng, et al. Thermodynamic performance simulation of NH3 based chemically recuperated cycle gas turbine[J]. Journal of Aerospace Power, 2024, 39（12）：20220993 doi: 10.13224/j.cnki.jasp.20220993
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The chemically recuperated cycle gas turbine is a promising NH3-fueled gas turbine, as it could improve the thermal efficiency and premixed burning stability effectively by partially decomposing NH3 into NH3/H2/N2 blended mixture with exhaust heat. The effects of catalyst activities (e.g. chemical equilibrium state and various Ru-based catalysts) on overall thermodynamic performance of a chemically recuperated gas turbine (CRGT) at off-design cases were investigated. Results indicated that: while thermal efficiency of a simple cycle gas turbine was about 30.5%—39% within net power ranges of 12—26 MW, it was about 40.4%—50.5% of a CRGT cycle at the equilibrium state and about 37.8%—46.6% over the Ru-based catalysts. For a certain catalyst and a constant gas hourly space velocity, the NH3 conversation rates varied slightly at off-design cases of a CRGT cycle, which was about 95% at the equilibrium state and about 40% over a Ru-based catalyst. Correspondingly, the chemical reaction heat per overall recuperated waste heat were about 56.5% and 32%, respectively. Furthermore, the low heating value (LHV) could be relatively improved about 13.3% and 5.4% by NH3 cracking in chemical recuperation system at the equilibrium state and Ru-based catalyst. Generally, the premixed flame could be stabilized significantly in a NH3-CRGT over a certain Ru-based catalyst.
| [1] |
SORRENTI I,RASMUSSEN T H,YOU S,et al. The role of power-to-X in hybrid renewable energy systems: a comprehensive review[J]. Renewable and Sustainable Energy Reviews,2022,165: 112380. doi: 10.1016/j.rser.2022.112380
|
| [2] |
HASAN M H,MAHLIA T M I,MOFIJUR M,et al. A comprehensive review on the recent development of ammonia as a renewable energy carrier[J]. Energies,2021,14: 3732. doi: 10.3390/en14133732
|
| [3] |
AYVAL T,TSANG S C E,VRIJALDENHOVEN T V. The position of ammonia in decarbonizing maritime industry: an overview and perspectives: Part I[J]. Johnson Matthey Technology Review,2021,65(2): 275-290. doi: 10.1595/205651321X16043240667033
|
| [4] |
STÉPHANIE B,ARACELI F P,CHRISTOPHE M,et al. Net zero by 2050: a roadmap for the global energy sector[EB/OL]. (2021-05-18) [2022-12-18].https://www.iea.org/reports/net-zero-by-2050.
|
| [5] |
KOBAYASHI H,HAYAKAWA A,SOMARATHNE K A,et al. Science and technology of ammonia combustion[J]. Proceedings of the Combustion Institute,2019,37(1): 109-133. doi: 10.1016/j.proci.2018.09.029
|
| [6] |
HAYAKAWA A,ARAKAWA Y,MIMOTO R,et al. Experimental investigation of stabilization and emission characteristics of ammonia/air premixed flames in a swirl combustor[J]. International Journal of Hydrogen Energy,2017,42(19): 14010-14018. doi: 10.1016/j.ijhydene.2017.01.046
|
| [7] |
KURATA O,IKI N,INOUE T,et al. Development of a wide range-operable,rich-lean low-NOx combustor for NH3 fuel gas-turbine power generation[J]. Proceedings of the Combustion Institute,2019,37(4): 4587-4595. doi: 10.1016/j.proci.2018.09.012
|
| [8] |
CHAI W S,BAO Y,JIN P,et al. A review on ammonia,ammonia-hydrogen and ammonia-methane fuels[J]. Renewable and Sustainable Energy Reviews,2021,147: 111254. doi: 10.1016/j.rser.2021.111254
|
| [9] |
KURATA O,IKI N,MATSUNUMA T,et al. Performances and emission characteristics of NH3-air and NH3CH4-air combustion gas-turbine power generations[J]. Proceedings of the Combustion Institute,2017,36(3): 3351-3359. doi: 10.1016/j.proci.2016.07.088
|
| [10] |
VALERA-MEDINA A,MORRIS S,RUNYON J,et al. Ammonia,methane and hydrogen for gas turbines[J]. Energy Procedia,2015,75: 118-123. doi: 10.1016/j.egypro.2015.07.205
|
| [11] |
VALERA-MEDINA A,GUTESA M,XIAO H,et al. Premixed ammonia/hydrogen swirl combustion under rich fuel conditions for gas turbines operation[J]. International Journal of Hydrogen Energy,2019,44(16): 8615-8626. doi: 10.1016/j.ijhydene.2019.02.041
|
| [12] |
PASHCHENKO D,MUSTAFIN R,KARPILOV I. Efficiency of chemically recuperated gas turbine fired with methane: effect of operating parameters[J]. Applied Thermal Engineering,2022,212: 118578. doi: 10.1016/j.applthermaleng.2022.118578
|
| [13] |
VITTORIO T,FRANCESCO L. Low CO2 emissions chemically recuperated gas turbines fed by renewable methanol[J]. Applied Energy,2021,298: 117146. doi: 10.1016/j.apenergy.2021.117146
|
| [14] |
郑洪涛,张玉龙,杨仁. CRGT循环燃气轮机性能仿真[J]. 航空动力学报,2012,27(1): 118-123. ZHENG Hongtao,ZHANG Yulong,YANG Ren. Simulation research of the CRGT cycle gas turbine performance[J]. Journal of Aerospace Power,2012,27(1): 118-123. (in Chinese
ZHENG Hongtao, ZHANG Yulong, YANG Ren. Simulation research of the CRGT cycle gas turbine performance[J]. Journal of Aerospace Power, 2012, 27(1): 118-123. (in Chinese)
|
| [15] |
POPOV S K,SVISTUNOV I N,GARYAEV A B,et al. The use of thermochemical recuperation in an industrial plant[J]. Energy,2017,127: 44-51. doi: 10.1016/j.energy.2017.03.091
|
| [16] |
MUKHERJEE S,DEVAGUPTAPU S V,SVIRIPA A,et al. Low-temperature ammonia decomposition catalysts for hydrogen generation[J]. Applied Catalysis: B Environmental,2018,226: 162-181. doi: 10.1016/j.apcatb.2017.12.039
|
| [17] |
杨晓红. 化学回热循环燃气轮机参数匹配和性能分析[D]. 哈尔滨: 哈尔滨工程大学,2019. YANG Xiaohong. Parameter matching and performance analysis of chemically recuperated gas turbine[D]. Harbin: Harbin Engineering University,2019. (in Chinese
YANG Xiaohong. Parameter matching and performance analysis of chemically recuperated gas turbine[D]. Harbin: Harbin Engineering University, 2019. (in Chinese)
|
| [18] |
PASHCHENKO D,MUSTAFIN R. Ammonia decomposition in the thermochemical waste-heat recuperation systems: a view from low and high heating value[J]. Energy Conversion and Management,2022,251: 114959. doi: 10.1016/j.enconman.2021.114959
|
| [19] |
CHA J,LEE T,LEE Y J,et al. Highly monodisperse sub-nanometer and nanometer Ru particles confined in alkali-exchanged zeolite Y for ammonia decomposition[J]. Applied Catalysis B: Environmental,2021,283: 119627. doi: 10.1016/j.apcatb.2020.119627
|
| [20] |
CAO Chenfeng,WU Kai,ZHOU Chen,et al. Electronic metal-support interaction enhanced ammonia decomposition efficiency of perovskite oxide supported ruthenium[J]. Chemical Engineering Science,2022,257: 117719. doi: 10.1016/j.ces.2022.117719
|
| [21] |
WANG Ziqing,QU Yingmin,SHEN Xiaolong,et al. Ruthenium catalyst supported on Ba modified ZrO2 for ammonia decomposition to COx-free hydrogen[J]. International Journal of Hydrogen Energy,2019,44(14): 7300-7307. doi: 10.1016/j.ijhydene.2019.01.235
|
| [22] |
LORENZUT B,MONTINI T,PAVEL C C,et al. Embedded Ru@ZrO2 catalysts for H2 production by ammonia decomposition[J]. ChemCatChem,2010,2(9): 1096-1106. doi: 10.1002/cctc.201000097
|
| [23] |
SU Q,GU L,YAO Y,et al. Layered double hydroxides derived Ni x(Mg yAl zO n) catalysts: enhanced ammonia decomposition by hydrogen spillover effect[J]. Applied Catalysis: B Environmental,2017,201: 451-460. doi: 10.1016/j.apcatb.2016.08.051
|
| [24] |
LESMANA H,ZHU M,ZHANG Z,et al. Experimental and kinetic modelling studies of laminar flame speed in mixtures of partially dissociated NH3 in air[J]. Fuel,2020,278: 118428. doi: 10.1016/j.fuel.2020.118428
|
| [25] |
MEI B,ZHANG J,SHI X,et al. Enhancement of ammonia combustion with partial fuel cracking strategy: laminar flame propagation and kinetic modeling investigation of NH3/H2/N2/air mixtures up to 10 atm[J]. Combustion and Flame,2021,231: 111472. doi: 10.1016/j.combustflame.2021.111472
|
| [26] |
LESMANA H,ZHU M,ZHANG Z,et al. Experimental and kinetic modelling studies of flammability limits of partially dissociated NH3 and air mixtures[J]. Proceedings of the Combustion Institute,2021,38(2): 2023-2030. doi: 10.1016/j.proci.2020.06.248
|
| [27] |
范卫东,陈钧. 氨气燃烧强化措施及NOx控制策略研究进展[J]. 华中科技大学学报(自然科学版),2022,50(7): 14-23. FAN Weidong,CHEN Jun. Research progress of combustion enhancement and NOx control strategies for ammonia combustion[J]. Journal of Huazhong University of Science and Technology (Natural Science Edition),2022,50(7): 14-23. (in Chinese
FAN Weidong, CHEN Jun. Research progress of combustion enhancement and NOx control strategies for ammonia combustion[J]. Journal of Huazhong University of Science and Technology (Natural Science Edition), 2022, 50(7): 14-23. (in Chinese)
|
| [28] |
KHATEEB A A,GUIBERTI T F,ZHU X,et al. Stability limits and NO emissions of technically-premixed ammonia-hydrogen-nitrogen-air swirl flames[J]. International Journal of Hydrogen Energy,2020,45(41): 22008-22018. doi: 10.1016/j.ijhydene.2020.05.236
|
| [29] |
WISEMAN S,RIETH M,GRUBER A,et al. A comparison of the blow-out behavior of turbulent premixed ammonia/hydrogen/nitrogen-air and methane–air flames[J]. Proceedings of the Combustion Institute,2021,38(2): 2869-2876. doi: 10.1016/j.proci.2020.07.011
|
| [30] |
JI C,WANG Z,WANG D,et al. Experimental and numerical study on premixed partially dissociated ammonia mixtures[J]. International Journal of Hydrogen Energy,2021,47: 4171-4184.
|
| [31] |
VERKAMP F,HARDIN M,WILLIAMS J. Ammonia combustion properties and performance in gas-turbine burners[J]. Symposium on Combustion,1967,11(1): 985-992. doi: 10.1016/S0082-0784(67)80225-X
|
| [32] |
GOLDMANN A,DINKELACKER F. Approximation of laminar flame characteristics on premixed ammonia/hydrogen/nitrogen/air mixtures at elevated temperatures and pressures[J]. Fuel,2018,224: 366-378. doi: 10.1016/j.fuel.2018.03.030
|
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