Volume 41 Issue 8
Aug.  2026
Turn off MathJax
Article Contents
Article Navigation >  Journal of Aerospace Power  > 2026  >  41(8): 20250331
Li Yanming, Wang Quan, Liu Huan, et al. High-temperature oxidation mechanism of aluminide coatings on the surface of nickel-based single crystal superalloys[J]. Journal of Aerospace Power, 2026, 41（8）：20250331 doi: 10.13224/j.cnki.jasp.20250331
Citation: Li Yanming, Wang Quan, Liu Huan, et al. High-temperature oxidation mechanism of aluminide coatings on the surface of nickel-based single crystal superalloys[J]. Journal of Aerospace Power, 2026, 41（8）：20250331 doi: 10.13224/j.cnki.jasp.20250331
shu

High-temperature oxidation mechanism of aluminide coatings on the surface of nickel-based single crystal superalloys

doi: 10.13224/j.cnki.jasp.20250331

  • Shenyang Engine Research Institute，Aero Engine Corporation of China，Shenyang 110015，China

  • Received Date: 2025-07-15
    Available Online: 2026-04-05
    Abstract

  • Al coatings and Co-Al coatings are generally deposited on the substrate of nickel-based single crystal superalloys. A systematic study was conducted on the experimental samples after 200 h of oxidation in a high-temperature environment at 1000 ℃. The experimental data showed that the oxidation kinetics of both the alloy substrate and the two coatings materials exhibited a typical parabolic variation trend. Compared with the alloy substrate and Al coating, the oxidation rate of the Co-Al coating was significantly reduced. After the high-temperature oxidation experiment, a large number of hole structures and crack defects can be observed on the surface of the alloy substrate. The occurrence of internal oxidation and internal nitridation reactions significantly reduced the oxidation resistance of the material. Compared with the Al coating, the Al2O3 protective film formed by the Co-Al coating after high-temperature oxidation exhibited more excellent high-temperature resistance, with lower defect density, higher purity, and a denser structure. The experiment also found that the introduction of Co effectively delayed the phase transformation process from β-NiAl phase to γ'-Ni3Al phase, and the outward diffusion behavior of refractory metal elements was significantly inhibited, providing favorable conditions for the formation of a continuous and dense Al2O3 protective film.

     

    • FullText(HTML)
  • loading
    • References(29)
  • [1]
    赖建和. 航空发动机涡轮叶片冷却技术综述[J]. 新型工业化, 2021, 11(8): 39-40. Lai Jianhe. Summary of cooling technology for aero-engine turbine blades[J]. The Journal of New Industrialization, 2021, 11(8): 39-40. (in Chinese

    Lai Jianhe. Summary of cooling technology for aero-engine turbine blades[J]. The Journal of New Industrialization, 2021, 11(8): 39-40. (in Chinese)
    [2]
    高志坤, 王威, 李艳明, 等. 基于显微组织演变的涡轮叶片损伤分析[J]. 航空发动机, 2022, 48(1): 121-126. Gao Zhikun, Wang Wei, Li Yanming, et al. Damage analysis of turbine blades based on microstructure evolution[J]. Aeroengine, 2022, 48(1): 121-126. (in Chinese doi: 10.13477/j.cnki.aeroengine.2022.01.019

    Gao Zhikun, Wang Wei, Li Yanming, et al. Damage analysis of turbine blades based on microstructure evolution[J]. Aeroengine, 2022, 48(1): 121-126. (in Chinese) doi: 10.13477/j.cnki.aeroengine.2022.01.019
    [3]
    张俊峰, 胡锡文, 崔凯, 等. 涡轮叶片典型交叉肋结构的气热分析[J]. 风机技术, 2022, 64(1): 54-59. Zhang Junfeng, Hu Xiwen, Cui Kai, et al. Aero-thermal analysis of cross ribbed structure of turbine blade[J]. Compressor, Blower & Fan Technology, 2022, 64(1): 54-59. (in Chinese

    Zhang Junfeng, Hu Xiwen, Cui Kai, et al. Aero-thermal analysis of cross ribbed structure of turbine blade[J]. Compressor, Blower & Fan Technology, 2022, 64(1): 54-59. (in Chinese)
    [4]
    刘迪, 高潘, 蔡杰, 等. GH80A经强流脉冲电子束改性后的高温氧化行为研究[J]. 表面技术, 2018, 47(11): 157-165. Liu Di, Gao Pan, Cai Jie, et al. High temperature oxidation behavior of nickel-based superalloy GH80A treated by high-current pulsed electron beam[J]. Surface Technology, 2018, 47(11): 157-165. (in Chinese doi: 10.16490/j.cnki.issn.1001-3660.2018.11.023

    Liu Di, Gao Pan, Cai Jie, et al. High temperature oxidation behavior of nickel-based superalloy GH80A treated by high-current pulsed electron beam[J]. Surface Technology, 2018, 47(11): 157-165. (in Chinese) doi: 10.16490/j.cnki.issn.1001-3660.2018.11.023
    [5]
    郭磊, 高远, 叶福兴, 等. 航空发动机热障涂层的CMAS腐蚀行为与防护方法[J]. 金属学报, 2021, 57(9): 1184-1198. Guo Lei, Gao Yuan, Ye Fuxing, et al. CMAS corrosion behavior and protection method of thermal barrier coatings for aeroengine[J]. Acta Metallurgica Sinica, 2021, 57(9): 1184-1198. (in Chinese

    Guo Lei, Gao Yuan, Ye Fuxing, et al. CMAS corrosion behavior and protection method of thermal barrier coatings for aeroengine[J]. Acta Metallurgica Sinica, 2021, 57(9): 1184-1198. (in Chinese)
    [6]
    李一民, 王升正, 范苛, 等. 基于电站风机表面保护的热喷涂和聚合物涂层研究[J]. 风机技术, 2020, 62(4): 68-74. Li Yimin, Wang Shengzheng, Fan Ke, et al. Thermal spraying and polymer coating based on fan surface protection in power plant[J]. Compressor, Blower & Fan Technology, 2020, 62(4): 68-74. (in Chinese

    Li Yimin, Wang Shengzheng, Fan Ke, et al. Thermal spraying and polymer coating based on fan surface protection in power plant[J]. Compressor, Blower & Fan Technology, 2020, 62(4): 68-74. (in Chinese)
    [7]
    陈景阳, 荆甫雷, 杨俊杰. 镍基单晶高温合金热机械疲劳行为与寿命建模[J]. 航空动力学报, 2021, 36(5): 897-906. Chen Jingyang, Jing Fulei, Yang Junjie. Thermo-mechanical fatigue behavior and life modelling in nickel based single crystal superalloy[J]. Journal of Aerospace Power, 2021, 36(5): 897-906. (in Chinese doi: 10.13224/j.cnki.jasp.2021.05.001

    Chen Jingyang, Jing Fulei, Yang Junjie. Thermo-mechanical fatigue behavior and life modelling in nickel based single crystal superalloy[J]. Journal of Aerospace Power, 2021, 36(5): 897-906. (in Chinese) doi: 10.13224/j.cnki.jasp.2021.05.001
    [8]
    郭殿品, 张尊礼, 张凡云, 等. 耐热扩散涂层在燃气轮机上的应用现状及趋势[J]. 腐蚀科学与防护技术, 2005, 17(1): 59-62. Guo Dianpin, Zhang Zunli, Zhang Fanyun, et al. High temperature corrosion resistant coatings for parts of gas turbines hot section[J]. Corrosion Science and Protection Technology, 2005, 17(1): 59-62. (in Chinese

    Guo Dianpin, Zhang Zunli, Zhang Fanyun, et al. High temperature corrosion resistant coatings for parts of gas turbines hot section[J]. Corrosion Science and Protection Technology, 2005, 17(1): 59-62. (in Chinese)
    [9]
    李克, 张莉, 丁志敏. 复杂型腔空心叶片气相渗铝工程化应用研究[J]. 航空制造技术, 2016, 59(20): 41-44. Li Ke, Zhang Li, Ding Zhimin. Research on engineering application for vapor aluminizing process of hollow blade[J]. Aeronautical Manufacturing Technology, 2016, 59(20): 41-44. (in Chinese doi: 10.16080/j.issn1671-833x.2016.20.041

    Li Ke, Zhang Li, Ding Zhimin. Research on engineering application for vapor aluminizing process of hollow blade[J]. Aeronautical Manufacturing Technology, 2016, 59(20): 41-44. (in Chinese) doi: 10.16080/j.issn1671-833x.2016.20.041
    [10]
    Liu P S, Liang K M, Gu S R. High-temperature oxidation behavior of aluminide coatings on a new cobalt-base superalloy in air[J]. Corrosion Science, 2001, 43(7): 1217-1226. doi: 10.1016/S0010-938X(00)00137-2
    [11]
    Liu P S, Liang K M. A new way to evaluate the high-temperature oxidation life of aluminide coatings on co-base superalloys in air[J]. Surface and Coatings Technology, 2000, 126(1): 64-68. doi: 10.1016/S0257-8972(00)00519-3
    [12]
    Yang Shiwei, Zhang Fanyun, Li Li, et al. High temperature oxidation morphology of Al-Si coating on the superalloy K438[J]. High Temperature Material Processes (an International Quarterly of High-Technology Plasma Processes), 2005, 9(4): 619-624. doi: 10.1615/HighTempMatProc.v9.i4.110
    [13]
    Yang S, Liu H, Zhu L, et al. High temperature oxidation resistance of Al-Si coating on K4104 superalloy[J]. Journal of Chinese Society for Corrosion and Protection, 2006, 26(6): 371-375. doi: 10.1615/hightempmatproc.v9.i4.110
    [14]
    Ma Jiaojiao, Meng Chuiyi, Wang Hui, et al. Effect of Al content on the high-temperature oxidation resistance and structure of CrAl coatings[J]. Coatings, 2021, 11(12): 1434. doi: 10.3390/coatings11121434
    [15]
    Vialas N, Monceau D. Effect of Pt and Al content on the long-term, high temperature oxidation behavior and interdiffusion of a Pt-modified aluminide coating deposited on Ni-base superalloys[J]. Surface and Coatings Technology, 2006, 201(7): 3846-3851. doi: 10.1016/j.surfcoat.2006.07.246
    [16]
    Ebach-stahl A, Fröhlich M. Oxidation study of Pt-Al based coatings on γ-TiAl at 950 ℃[J]. Surface and Coatings Technology, 2016, 287: 20-24. doi: 10.1016/j.surfcoat.2015.12.043
    [17]
    Das D K. Microstructure and high temperature oxidation behavior of Pt-modified aluminide bond coats on Ni-base superalloys[J]. Progress in Materials Science, 2013, 58(2): 151-182. doi: 10.1016/j.pmatsci.2012.08.002
    [18]
    Ren Weipeng, Xiao Chengbo, Li Qing, et al. Microstructure evolution of cobalt aluminide coating on nickel-based superalloys during exposure at 1050 ℃[J]. Vacuum, 2014, 106: 39-45. doi: 10.1016/j.vacuum.2014.03.013
    [19]
    任维鹏, 李青, 黄强, 等. 定向凝固镍基高温合金DZ466表面CoAl涂层的氧化及组织演变[J]. 金属学报, 2018, 54(4): 566-574. Ren Weipeng, Li Qing, Huang Qiang, et al. Oxidation and microstructure evolution of CoAl coating on directionally solidified Ni-based superalloys DZ466[J]. Acta Metallurgica Sinica, 2018, 54(4): 566-574. (in Chinese doi: 10.11900/0412.1961.2017.00240

    Ren Weipeng, Li Qing, Huang Qiang, et al. Oxidation and microstructure evolution of CoAl coating on directionally solidified Ni-based superalloys DZ466[J]. Acta Metallurgica Sinica, 2018, 54(4): 566-574. (in Chinese) doi: 10.11900/0412.1961.2017.00240
    [20]
    李艳明, 李中生, 刘欢, 等. 镍基高温合金表面Co-Al涂层抗高温氧化性能研究[J]. 航空发动机, 2023, 49(1): 169-174. Li Yanming, Li Zhongsheng, Liu Huan, et al. Research on high temperature oxidation resistance of co-Al coatings on Ni-based superalloy[J]. Aeroengine, 2023, 49(1): 169-174. (in Chinese doi: 10.13477/j.cnki.aeroengine.2023.01.025

    Li Yanming, Li Zhongsheng, Liu Huan, et al. Research on high temperature oxidation resistance of co-Al coatings on Ni-based superalloy[J]. Aeroengine, 2023, 49(1): 169-174. (in Chinese) doi: 10.13477/j.cnki.aeroengine.2023.01.025
    [21]
    戴建伟, 易军, 王占考, 等. 单晶高温合金铂改性铝化物涂层的高温氧化行为[J]. 航空材料学报, 2015, 35(5): 32-38. Dai Jianwei, Yi Jun, Wang Zhankao, et al. High temperature oxidation behavior of Pt modified aluminide coating on single crystal superalloy[J]. Journal of Aeronautical Materials, 2015, 35(5): 32-38. (in Chinese doi: 10.11868/j.issn.1005-5053.2015.5.006

    Dai Jianwei, Yi Jun, Wang Zhankao, et al. High temperature oxidation behavior of Pt modified aluminide coating on single crystal superalloy[J]. Journal of Aeronautical Materials, 2015, 35(5): 32-38. (in Chinese) doi: 10.11868/j.issn.1005-5053.2015.5.006
    [22]
    Liu He, Li Shuai, Jiang Chengyang, et al. Oxidation performance and interdiffusion behavior of a Pt-modified aluminide coating with pre-deposition of Ni[J]. Acta Metallurgica Sinica (English Letters), 2019, 32(12): 1490-1500. doi: 10.1007/s40195-019-00918-y
    [23]
    杨世伟, 张志明, 潘健全, 等. 镍基高温合金渗Al-Si涂层抗高温氧化性能研究[J]. 热加工工艺, 2007, 36(20): 59-61. Yang Shiwei, Zhang Zhiming, Pan Jianquan, et al. Study on high temperature oxidation properties of Al-Si coatings on superalloy[J]. Hot Working Technology, 2007, 36(20): 59-61. (in Chinese doi: 10.3969/j.issn.1001-3814.2007.20.020

    Yang Shiwei, Zhang Zhiming, Pan Jianquan, et al. Study on high temperature oxidation properties of Al-Si coatings on superalloy[J]. Hot Working Technology, 2007, 36(20): 59-61. (in Chinese) doi: 10.3969/j.issn.1001-3814.2007.20.020
    [24]
    卢旭东, 王复利. Ni-Cr-Co-Mo-W-Ta-Al合金在900 ℃和 1000 ℃的高温氧化行为[J]. 材料研究学报, 2016, 30(8): 589-594. Lu Xudong, Wang Fuli. Isothermal oxidation behaviour of Ni-Cr-Co-Mo-W-Ta-Al superalloy at 900 ℃ and 1000 ℃[J]. Chinese Journal of Materials Research, 2016, 30(8): 589-594. (in Chinese doi: 10.11901/1005.3093.2016.163

    Lu Xudong, Wang Fuli. Isothermal oxidation behaviour of Ni-Cr-Co-Mo-W-Ta-Al superalloy at 900 ℃ and 1000 ℃[J]. Chinese Journal of Materials Research, 2016, 30(8): 589-594. (in Chinese) doi: 10.11901/1005.3093.2016.163
    [25]
    王鑫, 许振华, 彭超, 等. 单晶高温合金铂改性铝化物涂层的高温防护性能研究[J]. 真空, 2020, 57(3): 11-16. Wang Xin, Xu Zhenhua, Peng Chao, et al. High temperature protection properties of Pt modified aluminide coating on the single crystal superalloy[J]. Vacuum, 2020, 57(3): 11-16. (in Chinese doi: 10.13385/j.cnki.vacuum.2020.03.03

    Wang Xin, Xu Zhenhua, Peng Chao, et al. High temperature protection properties of Pt modified aluminide coating on the single crystal superalloy[J]. Vacuum, 2020, 57(3): 11-16. (in Chinese) doi: 10.13385/j.cnki.vacuum.2020.03.03
    [26]
    李艳明, 刘欢, 乔志, 等. 镍基高温合金DD5、DD10和DSM11热腐蚀行为比较[J]. 中国有色金属学报, 2020, 30(9): 2105-2115. Li Yanming, Liu Huan, Qiao Zhi, et al. Comparison on hot corrosion behaviors of Ni-base superalloy DD5, DD10 and DSM11[J]. The Chinese Journal of Nonferrous Metals, 2020, 30(9): 2105-2115. (in Chinese doi: 10.11817/j.ysxb.1004.0609.2020-36479

    Li Yanming, Liu Huan, Qiao Zhi, et al. Comparison on hot corrosion behaviors of Ni-base superalloy DD5, DD10 and DSM11[J]. The Chinese Journal of Nonferrous Metals, 2020, 30(9): 2105-2115. (in Chinese) doi: 10.11817/j.ysxb.1004.0609.2020-36479
    [27]
    范其香, 王铁钢, 刘艳梅, 等. 镍基高温合金上Co改性铝化物涂层的组织结构与耐蚀性能[J]. 中国表面工程, 2015, 28(5): 116-122. Fan Qixiang, Wang Tiegang, Liu Yanmei, et al. Microstructure and corrosion behavior of co modified aluminide coatings on Ni-based superalloy[J]. China Surface Engineering, 2015, 28(5): 116-122. (in Chinese doi: 10.11933/j.issn.1007-9289.2015.05.018

    Fan Qixiang, Wang Tiegang, Liu Yanmei, et al. Microstructure and corrosion behavior of co modified aluminide coatings on Ni-based superalloy[J]. China Surface Engineering, 2015, 28(5): 116-122. (in Chinese) doi: 10.11933/j.issn.1007-9289.2015.05.018
    [28]
    马春春, 孙建刚, 刘镇洋, 等. Co、Al共渗涂层的性能研究[J]. 热喷涂技术, 2016, 8(2): 30-35. Ma Chunchun, Sun Jiangang, Liu Zhenyang, et al. Study of CoAl coating by pack cementation process[J]. Thermal Spray Technology, 2016, 8(2): 30-35. (in Chinese doi: 10.3969/j.jssn.1674-7127.2016.02.007

    Ma Chunchun, Sun Jiangang, Liu Zhenyang, et al. Study of CoAl coating by pack cementation process[J]. Thermal Spray Technology, 2016, 8(2): 30-35. (in Chinese) doi: 10.3969/j.jssn.1674-7127.2016.02.007
    [29]
    闻明, 姜东慧, 陈志全, 等. 铂铝高温抗氧化涂层的制备及性能研究[J]. 贵金属, 2010, 31(3): 16-22. Wen Ming, Jiang Donghui, Chen Zhiquan, et al. Study on preparation and properties of Pt-Al high temperature oxidation-resistant coatings[J]. Precious Metals, 2010, 31(3): 16-22. (in Chinese doi: 10.3969/j.issn.1004-0676.2010.03.004

    Wen Ming, Jiang Donghui, Chen Zhiquan, et al. Study on preparation and properties of Pt-Al high temperature oxidation-resistant coatings[J]. Precious Metals, 2010, 31(3): 16-22. (in Chinese) doi: 10.3969/j.issn.1004-0676.2010.03.004
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF(3864.0KB)
    XML

    Article Metrics

    Article views (611) PDF downloads(58) Cited by()
    Proportional views
    Related

    Copyright © 《Journal of Aerospace Power》 All Rights Reserved.

    Supported by: Beijing Renhe Information Technology Co., Ltd.  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return