Abstract: According to heat and mass transfer theory,the heat transfer of surface boiling of hydrogen peroxide solution under decomposition process was analyzed.The basic relation of heat transfer coefficient was presented.Based on the experimental data in the range of concentration from 5% to 30%,it is shown that,surface heat transfer coefficient will increase with the heat flux,bulk temperature and concentration,and there exists a maximum value of temperature difference between wall and solution,which will decrease with the increase of heat flux,bulk temperature and concentration.