甲烷水蒸气重整强化管内换热的数值模拟
Numerical simulation of enhanced heat transfer in tubes using methane steam reforming
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摘要: 以圆管内壁催化剂薄层内发生甲烷水蒸气重整反应为研究对象,对层流条件下反应及换热进行了数值模拟,分析了催化剂活性、薄层厚度、入口气体流量、入口压力、入口温度以及反应物组分比对反应和换热的影响.结果表明:催化剂薄层内的吸热反应可以有效地增强换热,降低壁面温度;提高催化剂活性和增加薄层厚度,可以增加化学反应吸热量,降低壁面温度,但是当薄层厚度达到一定值时,再增加薄层厚度效果很小;入口流量越大,反应转化率越小,化学反应吸热量占总吸热量的比例越小;入口压力越大,反应吸热量越小,壁面温度越高;提高入口温度使得近入口处壁面温度升高,但是对下游壁面温度的影响很小;存在最佳的反应物组分比,从而获得较低的壁面温度和较高的出口氢气含量.Abstract: Convectional heat transfer with methane steam reforming was investigated in catalyst films on the walls of a tube.The study analyzed the effect of catalytic activity,film thickness,inlet gas flowrate,pressure,temperature and concentration on reaction and heat transfer.The results show that the heat transfer is efficiently enhanced by the endothermic reaction in the catalyst films,and the wall temperature is reduced.Increased catalytic activity and film thickness increase the reaction heat and reduce the wall temperature.However,the effect of the film thickness becomes less significant as the thickness reaches a certain value.As the inlet flowrate increases,the conversion rate and the ratio of reaction heat decrease.As the inlet pressure increases,the reaction heat decreases and the wall temperature increases.As the inlet temperature increases,the wall temperature near the inlet increases,but this effect is very small on the wall temperatures downstream.There is an optimal inlet concentration,which corresponds to the lowest wall temperature and the highest hydrogen fraction at the outlet.
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Key words:
- thermal protection /
- enhanced heat transfer /
- methane /
- steam reforming /
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[1] Huang H,Spadaccini L J,Sobel D R.Fuel-cooled thermal management for advanced aeroengines[J].Journal of Engineering for Gas Turbines and Power,2004,126(2):284-293. [2] Kurganov V A,Zeigarnik Y A,Korabelnikov A V,et al.Thermochemical principle of cooling based on steam conversion of methane[J].Thermal Engineering,1996,143(3):198-210. [3] Glickstein M R,Spadaccini L J.Applications of endothermic reaction technology to the high speed civil transport .NASA Contractor Report 207404,1998. [4] Kuranov A,Korabelnikov A.Hypersonic technologies of atmospheric cruise flight under Ajax concept .AIAA 2008-2524,2008. [5] Kuranov A,Korabelnikov A.Catalytic structures for thermochemical protection and fuel conversion .AIAA 2009-7223,2009. [6] Kuranov A,Korabelnikov A.Hydrocarbon fuel conversion in the thermal protection reactor .AIAA 2009-7376,2009. [7] Korabelnikov A,Kuranov A L.Hypersonic flight vehicle heat protection using chemical heat regeneration .AIAA 2002-0913,2002. [8] Kuranov A,Korabelnikov A.Atmospheric cruise flight challenges for hypersonic vehicles under the Ajax concept[J].Journal of Propulsion and Power,2008,24(6):1229-1247. [9] 刘峰,姜培学,He S.催化剂薄层内甲烷水蒸气重整反应强化管内对流换热的数值模拟[J].工程物理学报,2006,27(6):987-989. LIU Feng,JIANG Peixue,He S.Numerical simulation of enhanced convection heat transfer using methane-steam reforming in catalyst films in a vertical tube[J].Journal of Engineering Thermophysics,2006,27(6):987-989.(in Chinese) [10] 刘峰.催化剂薄层内甲烷水蒸气重整反应强化管内对流换热研究 .北京:清华大学,2005. LIU Feng.Enhanced convection heat transfer using methan-steam reforming in catalyst films in vertical tubes .Beijing:Tsinghua University,2005.(in Chinese) [11] Xu J,Gilbert F F.Methane steam reforming,methanation and water-gas shift Ⅰ:intrinsic kinetics[J].AIChE Journal,1989,35(1):88-96. [12] 李绍芬.化学与催化反应工程[M].北京:化学工业出版社,1986. LI Shaofen.Chemical and catalytic reaction engineering[M].Beijing:Chemical Industry Press,1986.(in Chinese) [13] 贾力.高等传热学[M].北京:高等教育出版社,2003. JIA Li.Advanced heat transfer[M].Beijing:Higher Education Press,2003.(in Chinese)
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