Epoxy resin formulation and its composite properties for high efficiency wet winding
-
摘要: 针对高质固体火箭发动机壳体高效的生产要求对不同官能度环氧树脂复配体系的工艺性进行研究,重点开展了多官能团环氧树脂复配体系配方设计及力学性能研究,分别采用DSC(差示扫描分析)、黏度测试进行固化特征温度、固化反应动力学及工艺适用期研究,并最终制备单向层合板及NOL(the Naval Ordnance Laboratory)环进行复合材料性能的测试分析。研究结果表明:三官能度复配的环氧树脂能满足高效湿法缠绕要求。当三官能度的TDE-85质量分数为25%时,综合性能达到最优,适用期仅为120 min,拉伸强度为973 MPa,弯曲强度为115 MPa,玻璃化转变温度高达466 K,较最低值分别提高363%、159%、258%。该树脂体系与纤维匹配性好,复合材料性能优良,NOL环拉伸强度与层间剪切强度分别为256 GPa、744 MPa,纤维强度利用率达766%,适用于固体火箭发动机湿法缠绕成形。Abstract: According to the requirement for high-efficient production of high quality solid rocket motor shell, the epoxy resin formulation with different functionalities was studied by focusing on its formulation design and mechanical properties. The curing characteristic temperature, curing reaction kinetics and pot life were tested by DSC (differential scanning calorimetry) and viscosity test, respectively, the unidirectional laminates and NOL (the Naval Ordnance Laboratory) rings were prepared to test and analyze the properties of composites. The results showed that the epoxy resin with three functionalities can meet the requirements of high efficient wet winding. When the mass fraction of TDE-85 with three functionalities was 25%, the comprehensive properties reached the optimum, the tensile strength (973 MPa), the bending strength (115 MPa) and the glass transition temperature (466 K) increased by 363%, 159% and 258% respectively, while the applicable period was 120 min. The resin system had good adaptability to fibers, demonstrated by the excellent properties of composites, about 256 GPa in tensile strength and 744 MPa in interlaminar shear strength of the NOL rings, respectively. The utilization ratio of fiber strength reached 766%, demonstrating that the epoxy resin system was suitable for the wet winding process of the solid rocket motor.
-
Key words:
- solid rocket motor shell /
- composites /
- high efficiency wet winding /
- epoxy resin /
- functionality
-
[1] XU Yilei,DAYO A Q,WANG Jun,et al.Mechanical and thermal properties of a room temperature curing epoxy resin and related hemp fibers reinforced composites using a novel in-situ generated curing agent[J].Materials Chemistry and Physics,2018,203:293-301. [2] 沙云东,陈祎航,郝燕平,等.纤维增强复合材料涡轮轴结构疲劳寿命预测[J].航空动力学报,2017,32(4):769-779. SHA Yundong,CHEN Yihang,HAO Yanping,et al.Fatigue life prediction of fiber reinforced composites turbine shaft structure[J].Journal of Aerospace Power,2017,32(4):769-779.(in Chinese) [3] 宣海军,陆晓,洪伟荣,等.航空发动机机匣包容性研究综述[J].航空动力学报,2010,25(8):1860-1870. XUAN Haijun,LU Xiao,HONG Weirong,et al.Review of aero-engine case containment research[J].Journal of Aerospace Power,2010,25(8):1860-1870.(in Chinese) [4] TZENG J,EMERSON R,MOY P.Composite flywheels for energy storage[J].Composites Science and Technology,2006,66(14):2520-2527. [5] 何东晓.先进复合材料在航空航天的应用综述[J].高科技纤维与应用,2006,31(2):9-12. HE Dongxiao.Review of the application of advanced composite in aviation and aerospace[J].Hi-Tech Fiber and Application,2006,31(2):9-11.(in Chinese) [6] SHOTTON G,HARRY N E.Clean filament winding:process optimization[D].Birmingham,UK:University of Birmingham,2013. [7] PANDITA S,IRFAN M,MACHAVARAM V,et al.Clean wet-filament winding:Part 1 design concept and simulations[J].Journal of Composite Materials,2013,47(3):379-390. [8] DENG B,SHI Y,YU T,et al.Multi-response parameter interval sensitivity and optimization for the composite tape winding process[J].Materials,2018,11(2):220-240. [9] HIROSHIMA N,HATTA H,KOYAMA M,et al.Optimization of flywheel rotor made of three-dimensional composites[J].Composite Structures,2015,131:304-311. [10] 苏维国,张贤彪,魏锟,等.复合材料纤维张力缠绕预应力场动态特性[J].复合材料学报,2019,36(5):1143-1150. SU Weiguo,ZHANG Xianbiao,WEI Kun,et al.Pre-stress dynamic performance during filament winding with tension[J].Acta Materiae Compositae Sinica,2019,36(5):1143-1150.(in Chinese) [11] CHEN W,YU Y,LI P,et al.Effect of new epoxy matrix for T800 carbon fiber/epoxy filament wound composites[J].Composites Science and Technology,2007,67(11/12):2261-2270. [12] ZHANG Q,LI X,LIANG S,et al.A kind of liquid-like MWCNT reinforcements for T1000 carbon fiber filament winding composites[J].Composites Science and Technology,2016,131:89-97. [13] WANG C R,GU Y Z,ZHANG K M,et al.Rapid curing epoxy resin and its application in carbon fiber composite fabricated using VARTM moulding[J].Polymers & Polymer Composites,2013,21(5):315-323. [14] 李海东,程凤梅,周文英,等.一种水容器壳体湿法缠绕环氧树脂体系[J].复合材料学报,2005,22(3):40-44. LI Haidong,CHENG Fengmei,ZHOU Wenying,et al.Epoxy resin system for the pressure vessel of water treatment with wet fiber winding[J].Acta Materiae Compositae Sinica,2005,22(3):40-44.(in Chinese) [15] 李默宇.碳纤维湿法缠绕用高模量高韧性环氧树脂基体[D].北京:北京化工大学,2008. LI Moyu.Toughness epoxy resin with high modulus for carbon fiber wet filament winding[D].Beijing:Beijing University of Chemical Technology,2008.(in Chinese) [16] 李婷婷,李艳霞,陈超,等.603环氧树脂体系固化动力学模型的建立与验证[J].复合材料学报,2018,35(1):95-102. LI Tingting,LI Yanxia,CHEN Chao,et al.Establishment and verification of curing kinetics model of 603 epoxy resin system[J].Acta Materiae Compositae Sinica,2018,35(1):95-102.(in Chinese) [17] 孙曼灵.环氧树脂应用原理与技术[M].北京:机械工业出版社,2002. [18] 亓淑源,李波,李刚,等.RTM快速成型环氧树脂TTT图的构建及其碳纤维/环氧树脂复合材料评价[J].复合材料学报,2019,36(8):1804-1812. QI Shuyuan,LI Bo,LI Gang,et al.Establishment of time-temperature-transfer diagram of epoxy resin for rapid RTM process and evaluation of carbon fiber/epoxy resin composites[J].Acta Materiae Compositae Sinica,2019,36(8):1804-1812.(in Chinese) [19] FENG L,WANG Y,WANG Y,et al.Study on reaction kinetics of epoxy resin cured by a modified dicyandiamide[J].Journal of Applied Polymer Science,2012,127(3):1895-1900. [20] MA H,ZHANG X,JU F,et al.A study on curing kinetics of nano-phase modified epoxy resin[J].Scientific Reports,2018,8(1):3045-3049. [21] 陈平,蹇锡高,陈辉,等.碳纤维复合材料发动机壳体用韧性环氧树脂基体的研究[J].复合材料学报,2002,19(2):24-27. CHEN Ping,BI Xigao,CHEN Hui,et al.Study of toughened epoxy resins matrix for carbon fiber composite emotor case[J].Acta Materiae Compositae Sinica,2002,19(2):24-27.(in Chinese)
点击查看大图
计量
- 文章访问数: 549
- HTML浏览量: 11
- PDF量: 567
- 被引次数: 0