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基于HyChem方法的正丙基环己烷反应动力学模型

王光彩 王乾鹏 丁梦缘 王娟

王光彩, 王乾鹏, 丁梦缘, 王娟. 基于HyChem方法的正丙基环己烷反应动力学模型[J]. 航空动力学报, 2021, 36(7): 1452-1461. doi: 10.13224/j.cnki.jasp.20200417
引用本文: 王光彩, 王乾鹏, 丁梦缘, 王娟. 基于HyChem方法的正丙基环己烷反应动力学模型[J]. 航空动力学报, 2021, 36(7): 1452-1461. doi: 10.13224/j.cnki.jasp.20200417
WANG Guangcai, WANG Qianpeng, DING Mengyuan, WANG Juan. Reaction kinetic model of n-propylcyclohexane based on HyChem method[J]. Journal of Aerospace Power, 2021, 36(7): 1452-1461. doi: 10.13224/j.cnki.jasp.20200417
Citation: WANG Guangcai, WANG Qianpeng, DING Mengyuan, WANG Juan. Reaction kinetic model of n-propylcyclohexane based on HyChem method[J]. Journal of Aerospace Power, 2021, 36(7): 1452-1461. doi: 10.13224/j.cnki.jasp.20200417

基于HyChem方法的正丙基环己烷反应动力学模型

doi: 10.13224/j.cnki.jasp.20200417
基金项目: 

国家自然科学基金(U2032119,71690245)

详细信息
    作者简介:

    王光彩(1995-),男,硕士生,研究方向为燃料的化学反应动力学。

  • 中图分类号: V312+.1;TK16

Reaction kinetic model of n-propylcyclohexane based on HyChem method

  • 摘要: 采用Hybrid Chemistry (HyChem)建模方法对正丙基环己烷开展模型研究,以七步集总反应对大分子燃料热解形成小分子产物这一过程进行建模,小分子产物氧化过程则以小分子详细机理USC Mech Ⅱ进行描述。将两个子机理结合构建了正丙基环己烷的HyChem反应动力学模型(包括112个组分和791个基元反应),并通过流动管热解、点火延迟时间以及层流火焰速度的实验数据进行了模型验证。验证结果表明,正丙基环己烷HyChem反应动力学模型可以很好的预测正丙基环己烷热解过程中主要组分分布情况,在宏观燃烧参数的预测方面也有很好的表现,对点火延迟时间的计算相对误差为29.7%,对火焰传播速度的计算相对误差为11.1%。

     

  • [1] EDWARDS T,MAURICE L Q.Surrogate mixtures to represent complex aviation and rocket fuels[J].Journal of Propulsion and Power,2001,17(2):461-466.
    [2] DAGAUT P,KARSENTY F,DAYMAG,et al.Experimental and detailed kinetic model for the oxidation of agas to liquid (GtL) jet fuel[J].Combustion and Flame,2014,161(3):835-847.
    [3] SU Mengying,CHEN C P.Heating and evaporation of a new gasoline surrogate fuel:a discrete multicomponent modeling study[J].Fuel,2015,161(1):215-221.
    [4] WANG Quande,FANG Yamei,WANG Fan.Skeletal mechanism generation for high-temperature oxidation of kerosene surrogates[J].Combustion and Flame,2012,159(1):91-102.
    [5] DAGAUT P,DIEVART P.Combustion of synthetic jet fuels:naphthenic cut and blend with a gas-to-liquid (GtL) jet fuel[J].Proceedings of the Combustion Institute,2017,36(1):433-440.
    [6] WANG Qianpeng,WANG Cong,HUANG Yufei,et al.A kinetic study on pyrolysis of iso-propylcyclohexane:fuel structure effects of alkylcyclohexane isomers on reaction mechanisms[J].Proceedings of the Combustion Institute,2021,38(1):489-497.
    [7] 刘宇,曾文,马洪安,等.RP-3航空煤油3组分模拟替代燃料燃烧反应机理[J].航空动力学报,2016,31(9):2055-2064. LIU Yu,ZENG Wen,MA Hongan,et al.Combustion reaction mechanism of three-component simulation surrogate fuel for RP-3 kerosene[J].Journal of Aerospace Power,2016,31(9):2055-2064.(in Chinese)
    [8] 曾文,李海霞,马洪安,等.RP-3航空煤油3组分模拟替代燃料的化学反应详细机理[J].航空动力学报,2014,29(12):2810-2816. ZENG Wen,LI Haixia,MA Hongan,et al.Detailed chemical reaction mechanism of surrogate fuel for RP-3 kerosene[J].Journal of Aerospace Power,2014,29(12):2810-2816.(in Chinese)
    [9] 刘振涛,许全宏,张弛,等.煤基喷气燃料代用组分神经网络混合构建方法[J].航空动力学报,2016,31(11):2652-2658. LIU Zhentao,XU Quanhong,ZHANG Chi,et al.Surrogate formulation methodology of coal-based jet fuel based on neural network mixing model[J].Journal of Aerospace Power,2016,31(11):2652-2658.(in Chinese)
    [10] 曾文,刘靖,张治博,等.一种新的RP-3航空煤油模拟替代燃料[J].航空动力学报,2017,32(10):2314-2320. ZENG Wen,LIU Jing,ZHANG Zhibo,et al.A new surrogate fuel of RP-3 kerosene[J].Journal of Aerospace Power,2017,32(10):2314-2320.(in Chinese)
    [11] CROCHET M,MINETTI R,RIBAUCOUR M,et al.A detailed experimental study of n-propylcyclohexane autoignition in lean conditions[J].Combustion and Flame,2010,157(11):2078-2085.
    [12] DUBOIS T,CHAUMEIX N,PAILLARD C E.Experimental and modeling study of n-propylcyclohexane oxidation under engine-relevant conditions[J].Energy and Fuels,2009,23(5):2453-2466.
    [13] JI Chunsheng,DAMES E,SIRJEAN B.An experimental and modeling study of the propagation of cyclohexane and mono-alkylated cyclohexane flames[J].Proceedings of the Combustion Institute,2011,33:971-978.
    [14] COMANDINI A,DUBOIS T,CHAUMEIX N.Laminar flame speeds of n-decane,n-butylbenzene,and n-propylcyclohexane mixtures[J].Proceedings of the Combustion Institute,2015,35(1):671-678.
    [15] RISTORI A,DAGAUT P.Theoxidation of n-propylcyclo hexane:experimental results and kinetic modeling[J].Combustion Science and Technology,2001,165(1):197-228.
    [16] WANG Qianpeng,WANG Cong,HUANG Yufei,et al.Pyrolysis chemistry of n-propylcyclohexane via experimental and modeling approaches[J].Fuel,2021,283(1):118847.1-118847.11.
    [17] WANG Hai,XU Rui,WANG Kun,et al.A physics-based approach to modeling real-fuel combustion chemistry:Ⅰ evidence from experiments,and thermodynamic,chemical kinetic and statistical considerations[J].Combustion and Flame,2018,193:502-519.
    [18] XU Rui,WANG Kun,WANG Hai,et al.A physics-based approach to modeling real-fuel combustion chemistry:Ⅱ reaction kinetic models of jet and rocket fuels[J].Combustion and Flame,2018,193:520-537.
    [19] TAO Yujie,XU Rui,WANG Kun,et al.A Physics-based approach to modeling real-fuel combustion chemistry:Ⅲ reaction kinetic model of JP10[J].Combustion and Flame,2018,198:466-476.
    [20] WANG Hai,XU Rui,WANG Kun,et al.A physics-based approach to modeling real-fuel combustion chemistry:Ⅳ HyChem modeling of combustion kinetics of a bio-derived jetfuel and its blends with a conventional Jet A[J].Combustion and Flame,2018,198:477-489.
    [21] SAGGESE C,WAN K,WANG Hai,et al.A physics-based approach to modeling real-fuel combustion chemistry:Ⅴ NOx formation from a typical Jet A[J].Combustion and Flame,2020,212:270-278.
    [22] SAGGESE C,XU Rui,WANG Hai,et al.A physics-based approach to modeling real-fuel combustion chemistry:Ⅵ predictive kinetic models of gasoline fuels[J].Combustion and Flame,2020,220:475-487.
    [23] QI Fei.Combustion chemistry probed by synchrotron VUV photoionization mass spectrometry[J].Proceedings of the Combustion Institute,2013,34(1):33-63.
    [24] CHEN Dongping,WANG Kun,WANG Hai.Violation of collision limit in recently published reaction models[J].Combustion and Flame,2017,186(1):208-210.
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出版历程
  • 收稿日期:  2020-10-06
  • 刊出日期:  2021-07-28

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