Moisture absorption performance of composite stiffened panels in hygrothermal environment
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摘要:
为探究复合材料加筋板湿热环境下的吸湿性能,开展了70 ℃、水浴环境下复合材料加筋板吸湿试验,分析其吸湿量变化规律,并通过数据拟合进行验证。针对Fick吸湿模型的局限性,提出了考虑侧边吸湿效应的修正两阶段吸湿模型;同时基于有限元方法建立了加筋板吸湿性能有限元分析模型,模拟吸湿过程中加筋板内水分的扩散及分布规律。结果表明:试验中3件试验件饱和吸湿量分别为0.702%、0.696%和0.687%,且吸湿过程可分为前期线性快速吸湿和后期吸湿速率放缓直至平衡两个阶段。利用试验数据验证了修正模型计算结果的准确性,通过与文献对比证明了该模型可提高预测精度。通过有限元模型发现试件表面迅速达到吸湿平衡,薄板区域比厚板区域更快达到吸湿平衡状态。
Abstract:In order to investigate the moisture absorption performance of composite stiffened panels in hygrothermal environment, the moisture absorption experiment of composite stiffened panels under 70 ℃ and water bath environment was carried out to analyze the law of moisture absorption, and verified by data fitting. In view of the limitations of the Fick moisture absorption model, a modified two-stage moisture absorption model considering the side moisture absorption effect was proposed. At the same time, based on the finite element method, the analysis model of the moisture absorption performance of the stiffened panels was established to simulate the diffusion and distribution of moisture in the moisture absorption process. The results showed that the saturated moisture absorption of the three experiment specimens was 0.702%, 0.696% and 0.687%, respectively, and the moisture absorption process can be divided into two stages: linear rapid moisture absorption in the early stage and lower absorption rate until equilibrium in the later stage. The accuracy of the calculation results of the model was verified by using the experimental data, and comparison with the literature proved that the model can improve the prediction accuracy. Through the finite element model, the results exhibited that the surface of the specimen reached moisture absorption equilibrium rapidly, and the thin plate area reached moisture absorption equilibrium faster than the thick plate area.
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表 1 不同阶段的拟合方程数据
Table 1. Fitting equation data at different stages
参数 第Ⅰ阶段 第Ⅱ阶段 拟合方程 y=0.035x+232.98 y=−3×10−5x2+
0.009 8x+233.95拟合优度R2 0.9699 0.9885 -
[1] 益小苏. 航空复合材料科学与技术[M]. 北京: 航空工业出版社, 2013. [2] 贾振元,肖军,湛利华,等. 大型航空复合材料承力构件制造关键技术[J]. 中国基础科学,2019,21(2): 20-27. doi: 10.3969/j.issn.1009-2412.2019.02.003JIA Zhenyuan,XIAO Jun,ZHAN Lihua,et al. Research of large aviation and loading-bearing composite components manufacturing[J]. China Basic Science,2019,21(2): 20-27. (in Chinese) doi: 10.3969/j.issn.1009-2412.2019.02.003 [3] 周松,贾耀雄,许良,等. 湿热环境对T800碳纤维/环氧树脂基复合材料力学性能的影响[J]. 材料工程,2021,49(10): 138-143. doi: 10.11868/j.issn.1001-4381.2020.000954ZHOU Song,JIA Yaoxiong,XU Liang,et al. Effect of hygrothermal environment on mechanical properties of T800 carbon fiber/ epoxy resin composites[J]. Journal of Materials Engineering,2021,49(10): 138-143. (in Chinese) doi: 10.11868/j.issn.1001-4381.2020.000954 [4] 杨乃宾, 倪先平. 直升机复合材料结构设计[M]. 北京: 国防工业出版社, 2008. [5] 唐见茂. 碳纤维树脂基复合材料发展现状及前景展望[J]. 航天器环境工程,2010,27(3): 269-280. doi: 10.3969/j.issn.1673-1379.2010.03.001TANG Jianmao. Review of studies of carbon fiber resin matrix composites[J]. Spacecraft Environment Engineering,2010,27(3): 269-280. (in Chinese) doi: 10.3969/j.issn.1673-1379.2010.03.001 [6] 张纪奎,郦正能,程小全,等. 复合材料整体结构在大型民机上的应用[J]. 航空制造技术,2007,9(3): 38-44. doi: 10.3969/j.issn.1671-833X.2007.03.002ZHANG Jikui,LI Zhengneng,CHENG Xiaoquan,et al. Application of the composite material overall structure in large civil aircraft[J]. Aviation Manufacturing Technology,2007,9(3): 38-44. (in Chinese) doi: 10.3969/j.issn.1671-833X.2007.03.002 [7] FAGGIANI A,FALZON B G. Predicting low-velocity impact damage on a stiffened composite panel[J]. Composites: Part A,2010,41: 737-749. doi: 10.1016/j.compositesa.2010.02.005 [8] KIM H W,GRAYSON M A,NAIRN J A. Effect of hygrothermal aging on the microcrackling properties of some carbon fiber/polyimide laminates[J]. Advanced Composite Letters,1995,4: 185-192. [9] BROWNING C E. The mechanisms of elevated temperature property losses in high performance structural epoxy resin matrix materials after exposures to high humidity enviroments[J]. Polymer Engineering and Science,1978,18: 16-25. doi: 10.1002/pen.760180104 [10] 杜永,马玉娥. 湿热环境下纤维增强树脂基复合材料疲劳性能研究进展[J]. 复合材料学报,2022,39(2): 431-445. doi: 10.13801/j.cnki.fhclxb.20210828.001DU Yong,MA Yu’e. Fatigue performance of fiber reinforced polymer composites under hygrothermal environment: a review[J]. Acta Materiae Compositae Sinica,2022,39(2): 431-445. (in Chinese) doi: 10.13801/j.cnki.fhclxb.20210828.001 [11] 余海燕,吴航宇,石慧茹. 湿热环境中碳纤维复合材料层合板的强度退化及老化寿命预测[J]. 机械工程材料,2021,45(4): 40-45. doi: 10.11973/jxgccl202104008YU Haiyan,WU Yuhang,SHI Huiru. Strenth degradation and aging life prediction for carbon fiber reinforced polymers laminates in hygrothermal environment[J]. Materials for Mechanical Engineering,2021,45(4): 40-45. (in Chinese) doi: 10.11973/jxgccl202104008 [12] 吴以婷,葛东云,李辰. 湿热环境下Carbon/Epoxy复合材料层合板动态压缩性能[J]. 复合材料学报,2016,33(2): 259-264. doi: 10.13801/j.cnki.fhclxb.20150601.002WU Yiting,GE Dongyun,LI Chen. Dynamic compressive properties of Carbon/Epoxy composite laminates under hygrothermal environment[J]. Acta Materiae Compositae Sinica,2016,33(2): 259-264. (in Chinese) doi: 10.13801/j.cnki.fhclxb.20150601.002 [13] 牛一凡,李璋琪,朱晓峰. 全湿热场下碳纤维/环氧树脂复合材料层间剪切强度[J]. 高分子材料科学与工程,2021,37(4): 113-120. doi: 10.16865/j.cnki.1000-7555.2021.0111NIU Yifan,LI Zhangqi,ZHU Xiaofeng. Interlaminar shear strength of carbon fiber/epoxy composites under hygrothermal conditions[J]. Polymer Materials Science and Engineering,2021,37(4): 113-120. (in Chinese) doi: 10.16865/j.cnki.1000-7555.2021.0111 [14] 回丽,王勇刚,许良,等. 考虑水浸温度影响的复合材料吸湿动力学模型[J]. 材料工程,2016,44(11): 83-87. doi: 10.11868/j.issn.1001-4381.2016.11.014HUI Li,WANG Yonggang,XU Liang,et al. Moisture absorption model of composites considering water temperature effect[J]. Journal of Materials Engineering,2016,44(11): 83-87. (in Chinese) doi: 10.11868/j.issn.1001-4381.2016.11.014 [15] ZHANG Tiejun,LI Shulin,CHANG Fei,et al. An experimental and numerical analysis for stiffened composite panel subjected to shear loading in hygrothermal environment[J]. Composite Structures,2016,138: 107-115. doi: 10.1016/j.compstruct.2015.11.056 [16] FENG Yu,HE Yuting,AN Tao,et al. Effect of hygrothermal condition on buckling and post-buckling performance of CCF300/5228A aero composite stiffened panel under axial compression[J]. Journal of Reinforced Plastics & Composites,2015,34(12): 989-999. [17] 张先航,李曙林,常飞,等. BA9916-Ⅱ/CCF300复合材料加筋板吸湿特性[J]. 航空材料学报,2017,37(5): 63-69. doi: 10.11868/j.issn.1005-5053.2017.000038ZHANG Xianhang,LI Shulin,CHANG Fei,et al. BA9916-Ⅱ/CCF300 composite stiffened plate hygroscopic characteristics[J]. Journal of Aeronautical Materials,2017,37(5): 63-69. (in Chinese) doi: 10.11868/j.issn.1005-5053.2017.000038 [18] ASTM. Standard test method for moisture absorption properties and equilibrium conditioning of polymer matrix composite materials: ASTM D5229/D5229M [S]. West Conshohocken, PA: ASTM International, 2004: 1-20. [19] 赵晨,陈跃良,刘旭. 湿热条件下飞机聚合物基复合材料界面问题研究进展[J]. 装备环境工程,2012,9(5): 62-67.ZHAO Chen,CHEN Yueliang,LIU Xu. Research progress of interface of polymer matrix composites for aircraft in hot and humid environment[J]. Equipment Environmental Engineering,2012,9(5): 62-67. (in Chinese) [20] 高坤,史汉桥,孙宝岗,等. 湿热老化对玻璃纤维/环氧树脂复合材料性能的影响[J]. 复合材料学报,2016,33(6): 1147-1152. doi: 10.13801/j.cnki.fhclxb.20160108.001GAO Kun,SHI Hanqiao,SUN Baogang,et al. Effects of hydro-thermal aging on properties of glass fiber/epoxy composites[J]. Acta Materiae Compositae Sinica,2016,33(6): 1147-1152. (in Chinese) doi: 10.13801/j.cnki.fhclxb.20160108.001 [21] 张树永,罗小雯,李善君,等. 环氧树脂的吸水研究[J]. 化学通报,1997,64(8): 31-35. doi: 10.14159/j.cnki.0441-3776.1997.08.006ZHANG Shuyong,LUO Xiaowen,LI Shanjun,et al. Study on water absorption of epoxy resin[J]. Chemistry,1997,64(8): 31-35. (in Chinese) doi: 10.14159/j.cnki.0441-3776.1997.08.006 [22] 王红霞,万怡灶,王玉林. 玻璃纤维增强光固化树脂基复合材料吸湿性能的研究[J]. 玻璃钢/复合材料,2005,32(1): 33-36. doi: 10.3969/j.issn.1003-0999.2005.01.011WANG Hongxia,WAN Yizao,WANG Yulin. Study on moisture absorption of fiber reinforced light cured resin based composites[J]. Composites Science and Engineering,2005,32(1): 33-36. (in Chinese) doi: 10.3969/j.issn.1003-0999.2005.01.011 [23] ADAMS R D,SINGH M M. The dynamic properties of fibre-reinforced polymers exposed to hot, wet conditions[J]. Composites Science and Technology,1996,56(8): 977-997. doi: 10.1016/0266-3538(96)00065-6 [24] ZHOU Jiming,LUCAS J P. Hygrothermal effects of epoxy resin: Part Ⅰ the nature of water in epoxy[J]. Polymer,1999,40(20): 5505-5512. doi: 10.1016/S0032-3861(98)00790-3 [25] SHEN Chihung, SPRINGER G S. Moisture absorption and desorption of composite materials[J]. Journal of Composite Materials, 1976, 10(1): 2-20.