Calculation of thermophysical properties of supercritical RP-3 based on artificial neural network model
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摘要:
为准确得到超临界压力下RP-3的热物性,基于人工神经网络(ANN)方法建立超临界RP-3的密度、黏度、比定压热容和导热系数的计算模型。以广义对应态法则计算得到的RP-3热物性结果训练神经网络,并耦合了实验误差模型得到修正后的ANN模型。计算温度变化范围为300~800 K,压力变化范围为3~6 MPa。结果表明:ANN模型能准确地预测超临界RP-3的热物性,且计算精度比广义对应态法则计算得到的结果提高了16.3%。在压力为5 MPa的工况下,ANN模型预测的密度、黏度、比定压热容和导热系数的回归系数均大于0.99,与实验结果平均相对误差分别为1.5%、4.1%、0.9%和0.7%。
Abstract:In order to accurately obtain the thermophysical properties of RP-3 under supercritical pressure, the calculation models of density, viscosity, specific heat capacity at constant pressure and thermal conductivity of supercritical RP-3 were established based on artificial neural network (ANN) method. The RP-3 thermophysical properties obtained by the extended corresponding state were used to train the neural network, and the modified ANN model was obtained by coupling the experimental error model. The calculated temperature range was 300−800 K, and the pressure range was 3−6 MPa. The results showed that the ANN model can accurately predict the thermophysical properties of supercritical RP-3, and the calculation accuracy was 16.3% higher than that of the extended corresponding state. At the pressure of 5 MPa, the regression coefficients of density, viscosity, specific heat capacity at constant pressure and thermal conductivity predicted by the ANN model were all greater than 0.99. The mean relative errors with the experimental results were 1.5%, 4.1%, 0.9% and 0.7%, respectively.
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表 1 数据集划分方式
Table 1. Database partition mode
编号 温度范围/K 温度间隔/K 压力/MPa 集合 数量 1 300~800 0.1 3、4、6 训练集 15000 5 测试集 5000 2 300~800 1 3、4、6 训练集 1500 5 测试集 500 3 300~800 2 3、4、6 训练集 750 5 测试集 250 4 300~600600~700700~800 10.11 3、4、6 训练集 4200 5 测试集 1400 表 2 600~700 K范围内预测值平均相对误差小于2%的比例与模型收敛的迭代步长
Table 2. Proportion of mean relative error of predicted value less than 2% at temperature of 600−700 K and model convergence step
编号 平均相对误差小于2%的占比/% 迭代步长 密度 黏度 比定压热容 导热系数 1 100 100 100 100 602 2 83 81 76 100 98 3 63 59 92 100 44 4 100 100 100 100 239 表 3 ECS模型和ANN模型预测密度的结果
Table 3. Results of predicted density of ECS model and ANN model
区间 模型 Emr/% Emax/% 低温区
(300~600 K)ECS 1.3 2.4 ANN 0.4 1.8 临界区
(600~700 K)ECS 4.0 5.9 ANN 1.3 2.2 高温区(700~800 K) ECS 65.7 127.9 ANN 2.7 8.0 全区间 ECS 23.7 127.9 ANN 1.5 8.0 表 4 ECS模型和ANN模型预测黏度的结果
Table 4. Results of predicted viscosity of ECS model and ANN model
区间 模型 Emr/% Emax/% 低温区
(300~600 K)ECS 10.5 23.2 ANN 1.8 5.4 临界区
(600~700 K)ECS 20.8 28.4 ANN 5.9 9.0 高温区(700~800 K) ECS 17.3 31.2 ANN 4.7 18.5 全区间 ECS 16.2 31.2 ANN 4.1 18.5 表 5 ECS模型和ANN模型预测比定压热容的结果
Table 5. Results of predicted specific heat capacity at constant pressure of ECS model and ANN model
区间 模型 Emr/% Emax/% 低温区
(300~600 K)ECS 17.2 22.6 ANN 1.4 2.2 临界区
(600~700 K)ECS 24.8 26.7 ANN 0.6 1.0 高温区(700~800 K) ECS 32.4 37.2 ANN 0.6 2.6 全区间 ECS 24.8 37.2 ANN 0.9 2.6 表 6 ECS模型和ANN模型预测导热系数的结果
Table 6. Results of predicted thermal conductivity of ECS model and ANN model
区间 模型 Emr/% Emax/% 低温区
(300~600 K)ECS 17.1 20.6 ANN 0.5 0.9 临界区
(600~700 K)ECS 3.6 7.1 ANN 0.9 1.6 高温区(700~800 K) ECS 5.6 6.2 ANN 0.8 1.9 全区间 ECS 8.8 20.6 ANN 0.7 1.9 -
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