Study on surrogate model fuel and a methodology for developing skeletal mechanism for RP-3 aviation kerosene
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摘要:
提出了一种同时实现物理替代和化学替代的RP-3航空煤油模型燃料,该模型燃料由正十二烷、2, 5-二甲基己烷、 1, 3, 5-三甲基苯和十氢化萘组成,各组分的摩尔分数分别为0.54、0.22、0.14和0.1。针对现有骨架机理构建方法的局限性,提出了一种骨架机理构建方法,成功开发了包含153种组分和858个反应的高精度模型燃料骨架机理。通过系统验证,该模型燃料在物性参数(密度、黏度、喷雾贯穿距等)和基础燃烧特性(着火延迟时间、组分浓度变化、层流火焰传播特性、NO 排放等)方面均能较准确地预测RP-3燃油的物理化学行为。此外,数值模拟进一步证实该模型燃料可在853、898 K和923 K环境温度下准确预测 RP-3 燃油在定容燃烧室中的喷雾燃烧着火过程,充分验证了其物理和化学替代能力。该研究为高碳燃料模型燃料及机理构建提供了一种思路。
Abstract:An RP-3 aviation kerosene surrogate model fuel capable of both physical and chemical surrogate was proposed. The surrogate model fuel was composed of
n -dodecane, 2, 5-dimethylhexane, 1, 3, 5-trimethylbenzene and decalin, their molar fractions were 0.54, 0.22, 0.14 and 0.1, respectively. To overcome the limitations of existing skeletal mechanism construction methods, an approach was developed, leading to the successful establishment of a high-precision skeletal mechanism containing 153 species and 858 reactions. Through systematic validation, it was demonstrated that the proposed surrogate model fuel accurately predicted the physicochemical behavior of RP-3 fuel, including physical properties (density, viscosity, and spray penetration distance) and fundamental combustion characteristics (ignition delay time, species concentration evolution, laminar flame propagation, and NO emissions). Additionally, numerical simulations confirmed that the spray combustion and ignition processes of RP-3 fuel in a constant-volume combustion chamber at ambient temperatures of 853, 898 K, and 923 K can be effectively replicated, fully verifying its physical and chemical surrogate capabilities. This study could provide valuable insights into the development of high-carbon surrogate model fuel formulations and skeletal mechanisms. -
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