Experimental testing and numerical calculation of combustion and emission characteristics of natural gas coaxial staged combustor
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摘要:
对不同工况条件下某天然气燃气轮机同轴分级燃烧室点熄火、燃烧与排放特性进行了试验测试,并采用不同燃料的化学反应机理对该燃烧室的燃烧与排放特性进行了数值计算。结果表明:点火燃空比随进口空气流量的升高先降低后略有升高,熄火燃空比随进口空气压力的升高先降低后保持不变。随着燃空比的升高,燃烧室温升与出口平均温度逐渐升高,燃烧室出口NOx摩尔分数逐渐升高、CO摩尔分数基本不变、UHC摩尔分数先下降后上升;随着进口空气压力的升高,燃烧室温升与出口平均温度先升高后下降,燃烧室出口UHC、CO摩尔分数降低、NOx摩尔分数先下降后升高;随着进口空气温度的升高,燃烧室温升先升高后降低,出口平均温度升高,燃烧室出口UHC、CO摩尔分数降低、NOx摩尔分数升高。与采用甲烷的单步反应机理与详细反应机理相比,采用天然气的简化反应机理计算得到的该燃烧室温升、出口平均温度及主要排放物摩尔分数与相应试验数据之间的误差最小。同时,随着工况的升高,燃烧室内高温区域面积增加,燃烧室温升与出口平均温度升高,燃烧室出口NOx与CO2摩尔分数升高、CO摩尔分数降低。
Abstract:The ignition and blowout, combustion and emission characteristics of a coaxial staged combustion chamber of a natural gas turbine were experimentally tested, and the combustion and emission characteristics of the combustion chamber were numerically calculated by using the chemical reaction mechanisms of different fuels. The results showed that, the ignition fuel/air ratio decreased first and then slightly increased with the increase of inlet air flow, and the blowout fuel/air ratio decreased first and then remained unchanged with the increase of inlet air pressure. With the increase of fuel/air ratio, the temperature rise of the combustion chamber and the average temperature at the outlet of the combustion chamber gradually increased, and the NOx mole fraction gradually increased, the CO mole fraction remained unchanged, and the UHC mole fraction first decreased and then increased at the outlet of the combustion chamber. With the increase of inlet air pressure, the temperature rise and the outlet average temperature first increased and then decreased, and the mole fractions of UHC, CO decreased, and the mole fraction of NOx first decreased and then increased at the outlet of combustion chamber. With the increase of inlet air temperature, the temperature rise first increased and then decreased, the outlet average temperature gradually increased, and the mole fractions of UHC, CO gradually decreased and the mole fraction of NOx gradually increased at the outlet of combustion chamber. Compared with the single step reaction mechanism and the detailed reaction mechanism of methane, the outlet average temperature and major emissions' mole fractions calculated by the reduced reaction mechanism of natural gas had the smallest error between the corresponding experimental data. With the rise of the working condition, the high temperature area in the combustion chamber increased, the temperature rise and the outlet average temperature increased, the mole fractions of NOx and CO2 increased and the mole fraction of CO decreased at the outlet of combustion chamber.
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表 1 点熄火试验工况
Table 1. Experimental conditions of ignition and blowout
工况参数 点火工况 熄火工况 进口空气流量/(kg/s) 0.15,0.2,0.25 0.2 进口空气温度/K 313 313 进口空气压力/MPa 0.1 0.1,0.2,0.3 表 2 燃烧室燃烧与排放特性试验工况
Table 2. Experimental conditions of combustion and emission characteristics of the combustor
工况 燃空比 进口空气
流量/(kg/s)天然气
流量/(g/s)进口空气
温度/K进口空气
压力/MPa1 0.0187 0.2 3.739 313 0.1 2 0.0207 0.2 4.142 313 0.1 3 0.0227 0.2 4.402 313 0.1 4 0.0207 0.2 4.142 313 0.2 5 0.0207 0.2 4.142 313 0.3 6 0.0207 0.2 4.142 353 0.1 7 0.0207 0.2 4.142 393 0.1 表 3 燃烧室的温升、出口平均温度及 $ {{\boldsymbol{\delta}} }_{\bf{otdf}} $
Table 3. Temperature rise, outlet average temperature and $ {{\boldsymbol{\delta }}}_{\bf{otdf}} $ of the combustor
工况 平均温度/K 温升/K $ {\delta }_{\mathrm{o}\mathrm{t}\mathrm{d}\mathrm{f}} $ 1 1158.15 845.15 0.139 2 1247.45 934.45 0.125 3 1307.95 994.95 0.124 4 1271.95 958.95 0.155 5 1265.05 952.05 0.155 6 1328.55 975.55 0.114 7 1341.35 948.35 0.073 表 4 燃烧室出口排放物摩尔分数
Table 4. Emissions mole fractions at the combustor outlet
工况 排放物摩尔分数/10−4 UHC CO NOx 1 4.2375 3.7843 0.0888 2 2.9484 3.7255 0.0991 3 4.0419 3.6455 0.1023 4 2.4452 2.3608 0.0996 5 1.2985 0.8426 0.1026 6 1.9694 0.7832 0.1119 7 1.4963 0.6064 0.1152 表 5 燃烧室燃烧与排放特性计算工况
Table 5. Calculation conditions of combustion and emission characteristics of the combustor
工况 燃空比 进口空气
流量/(kg/s)天然气
流量/(g/s)进口空气
温度/K进口空气
压力/MPa1 0.0227 0.20 4.402 313.0 0.100 2 0.0207 1.304 26.99 508.4 0.585 3 0.0231 1.643 37.95 545.5 0.733 4 0.0260 2.035 52.91 581.3 0.899 5 0.0290 2.273 65.92 600.9 1.000 表 6 燃烧室温升与出口平均温度对比
Table 6. Comparisons of temperature rise and outlet average temperature of the combustor
工况 出口平均
温度/K出口平均
温度误差/%温升/K 温升
误差/%试验值 1307.95 994.95 单步反应机理 1113.84 14.84 800.84 19.51 详细反应机理 1225.69 6.29 912.69 8.27 简化反应机理 1278.01 2.29 965.01 3.01 表 7 主要排放物摩尔分数的试验值与数值计算结果对比
Table 7. Comparisons of the experimental and simulated major emissions mole fractions
工况 排放物摩尔分数/10−4 CO2 NOx CO 试验值 329 0.1023 3.6455 简化反应机理 369 0.1225 3.8922 详细反应机理 385 0.1231 3.9817 表 8 不同工况下燃烧室温升与出口平均温度
Table 8. Temperature rise and outlet average temperature of the combustor at different conditions
K 工况 出口平均温度 温升 2 1525.32 1016.92 3 1571.58 1026.08 4 1628.24 1046.94 5 1669.65 1068.75 表 9 不同工况下燃烧室出口主要排放物的摩尔分数
Table 9. Major emissions mole fractions at the outlet of the combustor at the different conditions
工况 排放物摩尔分数/10−4 CO2 NOx CO 2 303 0.0037 4.314 3 391 0.0050 1.161 4 474 0.0468 0.039 5 511 0.0919 0.038 -
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