Study on blending and combustion characteristics of hydrogen micro-mixing diffusion unit
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摘要:
为改善纯氢火焰的燃烧不稳定现象并降低NOx排放,基于氢气横向喷注的微混扩散燃烧单元开展相关研究,通过冷态、热态的数值仿真,探究微混段长度和燃料空气的动量通量比对掺混效果、火焰形态以及NOx排放的影响规律,并通过实验测量不同工况下微混单元的实际NOx排放。研究结果表明:当氢气穿透深度的不同时,火焰呈现托举火焰、“W”形火焰和水滴形火焰3种不同形态;为实现低NOx排放,被气流托举的火焰需要更优的掺混效果以维持稳定燃烧,而“W”形和水滴形这类能附着在微混单元出口的火焰则要防止火焰过于集中,反而应该适当降低掺混;NOx排放在当量比为0.7和0.8时较高,且随着空气流量的增加排放略有降低。
Abstract:To enhance the combustion stability of hydrogen flames and reduce NOx emissions, investigation was carried out on a micro-mixing diffusion unit with hydrogen cross-injection. By means of numerical simulations for the cold and combustion states, the impacts of the length of micro-mixing section and the momentum flux ratio between fuel and air on mixing efficiency, flame morphology, and NOx emissions were analyzed. Furthermore, experimental measurements were conducted to evaluate the actual NOx emissions of the micro-mixing diffusion unit under varied operating conditions. Results indicated that three distinct combustion modes emerged: lifted flame, “W”-shaped flame, and droplet flame while the hydrogen penetration depths were changed. To achieve lower NOx emissions, the lifted flame required enhanced mixing for stable combustion. However, the excessive flame concentration should be avoided by appropriately reducing mixing for “W”-shaped and droplet flames because flame was adhered to the outlet of the micro-mixing unit. NOx emissions were relatively higher at equivalence ratios of 0.7 and 0.8 but decreased as air flow rate increased.
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Key words:
- hydrogen /
- micro-mixing diffusion combustion /
- fuel blending /
- NOx emission /
- flame characteristics
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表 1 化学反应式
Table 1. Chemical reaction equation
序号 反应式 序号 反应式 1 H2+O2$\rightleftharpoons $HO2+H 18 OH+H2O2$\rightleftharpoons $H2O+HO2 2 H+O2$\rightleftharpoons $OH+O 19 OH+OH+M$\rightleftharpoons $H2O2+M 3 O+H2$\rightleftharpoons $OH+H 20 N+N+M$\rightleftharpoons $N2+M 4 OH+H2$\rightleftharpoons $H2O+H 21 N+O2$\rightleftharpoons $NO+O 5 OH+OH$\rightleftharpoons $H2O+O 22 N+NO$\rightleftharpoons $N2+O 6 H+OH+M$\rightleftharpoons $H2O+M 23 N+OH$\rightleftharpoons $NO+H 7 H+H+M$\rightleftharpoons $H2+M 24 H+NO+M$\rightleftharpoons $HNO+M 8 H+O+M$\rightleftharpoons $OH+M 25 H+HNO$\rightleftharpoons $NO+H2 9 O+O+M$\rightleftharpoons $O2+M 26 O+HNO$\rightleftharpoons $NO+OH 10 H+O2+M$\rightleftharpoons $HO2+M 27 OH+HNO$\rightleftharpoons $NO+H2O 11 HO2+H$\rightleftharpoons $OH+OH 28 HO2+HNO$\rightleftharpoons $NO+H2O2 12 HO2+O$\rightleftharpoons $O2+OH 29 HO2+NO$\rightleftharpoons $NO2+OH 13 HO2+OH$\rightleftharpoons $H2O+O2 30 HO2+NO$\rightleftharpoons $HNO+O2 14 HO2+HO2$\rightleftharpoons $H2O2+O2 31 H+NO2$\rightleftharpoons $NO+OH 15 H+H2O2$\rightleftharpoons $H2+HO2 32 O+NO2$\rightleftharpoons $NO+O2 16 H+H2O2$\rightleftharpoons $OH+H2O 33 M+NO2$\rightleftharpoons $NO+O+M 17 O+H2O2$\rightleftharpoons $OH+HO2 表 2 试验测量量程与允许误差(满量程)
Table 2. Measurement range and allowable error of experiment (full scale)
测量物理量 量程 允许误差 O2 0%~25% 0.1% NO 0~200×10−6 1% FS NO2 0~100×10−6 1% FS NOx 0~300×10−6 1% FS Tout 273~1 873 K 1.5 K 表 3 变量方案分组原理
Table 3. Principle of different schemes
方案 $ {d}_{2}/\mathrm{m}\mathrm{m} $ $ \varPhi $ $ J $ 工况1 0.4 0.4~0.8 计算$ {J}_{\mathrm{c}1} $ 工况2 计算$ {d}_{2J} $ 0.4~0.8 26.76 工况3 计算$ {d}_{2\varPhi } $ 0.6 11.90~47.58 表 4 $ {{\boldsymbol{J}}}_{\bf{c}1} $与$ {{\boldsymbol{d}}}_{{\boldsymbol{2}}{\boldsymbol{J}}}\mathrm{、}{{\boldsymbol{d}}}_{{\boldsymbol{2}}{\boldsymbol{\varPhi}} } $的计算值
Table 4. Calculated values of $ {\boldsymbol{J}}_{\bf{c}1} $, $ {\boldsymbol{d}}_{{\bf{2}}\boldsymbol{J}}\; \mathbf{a}\mathbf{n}\mathbf{d}\; {\boldsymbol{d}}_{{\bf{2}}\boldsymbol{\varPhi }} $
$ \varPhi $ $ {J}_{\mathrm{c}1} $ $ {d}_{2J}/\mathrm{m}\mathrm{m} $ $ {d}_{2\varPhi }/\mathrm{m}\mathrm{m} $ 0.4 11.90 0.3266 0.4899 0.5 18.59 0.3651 0.4382 0.6 26.76 0.4000 0.4000 0.7 36.43 0.432 0.3703 0.8 47.58 0.4619 0.3464 表 5 试验工况表
Table 5. Experimental operating condition
参数 取值 $ {v}_{\mathrm{a}} $/(m/s) 5、7、9 $ \varPhi $ 0.4、0.5、0.6、0.7、0.8 -
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