摘要: 研究了基于层流小火焰概念和假定beta-PDF(probability density function)的湍流预混燃烧模型.该模型采用PREMIX程序来计算层流小火焰,将计算结果表示为进程变量的函数,并利用进程变量的beta-PDF积分生成了用于RANS(雷诺平均Navier-Stokes)计算的PDF表.以化学当量的甲烷湍流本生火焰为算例对模型进行了计算验证,并与Zimont模型的计算结果和实验结果做了对比.结果表明,平均速度分布与实验符合的较好,温度和湍动能计算结果有待改善.本模型高估了化学反应速率,导致计算火焰比实际瘦,这是因为模型中未能考虑湍流对火焰的拉伸和弯曲效应,考虑湍流拉伸和弯曲效应的预混燃烧模型是今后进一步研究的方向.
摘要: The decomposition kinetic parameters of ammonium perchlorate (AP) having different grain size (10-390μm) were investigated through simultaneous DSC/TGA (differential scanning calorimetry/thermal gravimetric analysis) analyzer in a dynamic nitrogen atmosphere under heating rate of 40K/min.The kinetic parameters such as activation energy and pre-exponential factor were determined by the modified isoconversional method.The Brurzauer-Emmett-Teller (BET)-method was applied to measure AP specific surface areas.The results show that the higher the AP particle size the lower the determined kinetic parameters and are matched with some important literatures.